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浏览/检索结果: 共2条，第1-2条 帮助 限定条件 内容类型：期刊论文    发表日期：2014     已选(0)清除 条数/页：5101520253035404550556065707580859095100   排序方式：请选择发表日期升序发表日期降序提交时间升序提交时间降序题名升序题名降序作者升序作者降序 Ar-BINMOL-DERIVED SALAN-Cu(II) COMPLEX-CATALYZED SILYL-REFORMATSKY REACTION OF AROMATIC ALDEHYDES 期刊论文 Synthetic Communications, 2014, 卷号: 44, 期号: 19, 页码: 2861-2869 作者:  Li F(李菲);  Zhou, Wei;  Zheng LS(郑龙生);  Li L(李莉);  Zheng ZJ(郑战江) 收藏  |  浏览/下载：26/0  |  提交时间：2016/02/15 Ar-BINMOL  aromatic aldehydes  organosilicon chemistry  Reformatsky reaction  salan ligand   Synthesis, characterization, and ethylene polymerization behaviors of late-transition metal complexes coordinated with chlorinated bis(arylimino)pyridine ligand 期刊论文 polymer, 2014, 卷号: 55, 期号: 18, 页码: 4611-4618 Liu, Heng; Wang, Feng; Liu, Li; Jai,Xiang-Yu; Zheng,Wenjie; Guo,Jun; Zhang,Chun-Yu; Bai,Chen-Xi; Hu,Yan-Ming; Zhang,Xue-Quan 收藏  |  浏览/下载：20/0  |  提交时间：2015/10/20 A series of late-transition metal complexes supported with chlorinated bis(arylimino)pyridine ligands [2  Ar = 2  Ar = 2  Ar = 2  Ar = 4-Cl-2  Ar = 4-Br-2  6-(ArN=CCl)(2)C5H3N]MtCl(2) (Ar = 2  6-(Pr2C6H3)-Pr-i  6-Et2C6H3  6-Me2C6H3  6-Me2C6H2  6-Me2C6H2  4  Mt = Fe (1b)  Mt = Co (1c)  Mt = Fe (1d)  Mt = Fe (1e)  Mt = Fe (1f)  6-Me3C6H2  Co (2b)  Ni (3c)  Co (2d)  Co (2e)  Co (2f)) were synthesized. At the presence of methylaluminoxane (MAO)  Mt = Fe (1a)  Fe(II)- and Co(II)- based complexes were highly active towards ethylene polymerization  Co (2a)  affording polymers with bimodal and unimodal molar. mass distributions  Ni (3a)  respectively  while the Ni(II)-based complexes gave no polymer products. Moreover  the obtained polyethylenes were predominately saturated and vinyl-terminated for Fe(II)- and Co(II)-based complexes  respectively. Changing the ligand environment  polymerization parameters also posed a great influence on the catalytic activities and the properties of the resulting polymers. (C) 2014 Elsevier Ltd. All rights reserved.