Ar-BINMOL-DERIVED SALAN-Cu(II) COMPLEX-CATALYZED SILYL-REFORMATSKY REACTION OF AROMATIC ALDEHYDES

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	Ar-BINMOL-DERIVED SALAN-Cu(II) COMPLEX-CATALYZED SILYL-REFORMATSKY REACTION OF AROMATIC ALDEHYDES
	Li F(李菲)1; Zhou, Wei 1; Zheng LS(郑龙生)1; Li L(李莉)1; Zheng ZJ(郑战江)1; Xu LW(徐利文)1,2
刊名	Synthetic Communications
	2014
卷号	44 期号:19 页码:2861-2869
关键词	Ar-BINMOL aromatic aldehydes organosilicon chemistry Reformatsky reaction salan ligand
ISSN号	0039-7911
通讯作者	徐利文
英文摘要	In this work, we have developed a facile protocol with salan–Cu system for the facile and selective synthesis of β-hydroxyesters via silyl-Reformatsky reaction with α-silylester and aldehydes. The screening and optimization of reaction conditions led to the determination of a practical and efficient procedure in which the salan–Cu exhibited promising catalytic activity in dimethylsulfoxide, in which the silyl-Reformatsky reaction of aromatic aldehydes with α-trimethylsilylmethylacetate gave the corresponding β-hydroxyester derivatives in excellent yields (up to 98%) under fluoride-free reaction conditions.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the National Natural Science Founder of China (No. 21173064;51303043);Zhejiang Provincial Natural Science Foundation of China (LR14B030001;LQ12B02004);Program for Excellent Young Teachers in Hangzhou Nornal University (HNUEYT, JTAS 2011-01-04)
语种	英语
WOS记录号	WOS:000341513100011
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/19270]
专题	兰州化学物理研究所_OSSO国家重点实验室
作者单位	1.Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Coll Mat Chem & Chem Engn, Minist Educ, Hangzhou 310012, Zhejiang, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Li F,Zhou, Wei,Zheng LS,et al. Ar-BINMOL-DERIVED SALAN-Cu(II) COMPLEX-CATALYZED SILYL-REFORMATSKY REACTION OF AROMATIC ALDEHYDES[J]. Synthetic Communications,2014,44(19):2861-2869.
APA	Li F,Zhou, Wei,Zheng LS,Li L,Zheng ZJ,&Xu LW.(2014).Ar-BINMOL-DERIVED SALAN-Cu(II) COMPLEX-CATALYZED SILYL-REFORMATSKY REACTION OF AROMATIC ALDEHYDES.Synthetic Communications,44(19),2861-2869.
MLA	Li F,et al."Ar-BINMOL-DERIVED SALAN-Cu(II) COMPLEX-CATALYZED SILYL-REFORMATSKY REACTION OF AROMATIC ALDEHYDES".Synthetic Communications 44.19(2014):2861-2869.