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Synthesis, characterization, and ethylene polymerization behaviors of late-transition metal complexes coordinated with chlorinated bis(arylimino)pyridine ligand 期刊论文
polymer, 2014, 卷号: 55, 期号: 18, 页码: 4611-4618
Liu, Heng; Wang, Feng; Liu, Li; Jai,Xiang-Yu; Zheng,Wenjie; Guo,Jun; Zhang,Chun-Yu; Bai,Chen-Xi; Hu,Yan-Ming; Zhang,Xue-Quan
收藏  |  浏览/下载:20/0  |  提交时间:2015/10/20
A series of late-transition metal complexes supported with chlorinated bis(arylimino)pyridine ligands [2  Ar = 2  Ar = 2  Ar = 2  Ar = 4-Cl-2  Ar = 4-Br-2  6-(ArN=CCl)(2)C5H3N]MtCl(2) (Ar = 2  6-(Pr2C6H3)-Pr-i  6-Et2C6H3  6-Me2C6H3  6-Me2C6H2  6-Me2C6H2  4  Mt = Fe (1b)  Mt = Co (1c)  Mt = Fe (1d)  Mt = Fe (1e)  Mt = Fe (1f)  6-Me3C6H2  Co (2b)  Ni (3c)  Co (2d)  Co (2e)  Co (2f)) were synthesized. At the presence of methylaluminoxane (MAO)  Mt = Fe (1a)  Fe(II)- and Co(II)- based complexes were highly active towards ethylene polymerization  Co (2a)  affording polymers with bimodal and unimodal molar. mass distributions  Ni (3a)  respectively  while the Ni(II)-based complexes gave no polymer products. Moreover  the obtained polyethylenes were predominately saturated and vinyl-terminated for Fe(II)- and Co(II)-based complexes  respectively. Changing the ligand environment  polymerization parameters also posed a great influence on the catalytic activities and the properties of the resulting polymers. (C) 2014 Elsevier Ltd. All rights reserved.  
Synthesis, characterization, and 1,3-butadiene polymerization studies of Co(II), Ni(II), and Fe(II) complexes bearing 2-(N-arylcarboximidoylchloride)quinoline ligand 期刊论文
journal of molecular catalysis a-chemical, 2014, 卷号: 391, 期号: 52, 页码: 25-35
Liu, Heng; Wang, Feng; Jia, Xiang-Yu; Liu,Li; Bi,Ji-Fu; Zhang,Chun-Yu; Zhao,Li-Ping; Bai,Chen-Xi; Hu,Yan-Ming; Zhang,Xue-Quan
收藏  |  浏览/下载:28/0  |  提交时间:2015/10/20
Ligand Steric and Electronic Effects on beta-Ketiminato Neutral Nickel(II) Olefin Polymerization Catalysts 期刊论文
organometallics, 2012, 卷号: 31, 期号: 3, 页码: 966-975
Song DP; Shi XC; Wang YX; Yang JX; Li YS
收藏  |  浏览/下载:18/0  |  提交时间:2013/06/08
单组分酚膦中性镍催化乙烯均聚与共聚反应(英文) 期刊论文
应用化学, 2012, 卷号: 29, 期号: 12, 页码: 1381-1388
穆红亮; 李彦国; 李悦生
收藏  |  浏览/下载:20/0  |  提交时间:2013/11/17
Synthesis and characterization of novel neutral nickel complexes bearing fluorinated salicylaidiminato ligands and their catalytic behavior for vinylic polymerization of norbornene 期刊论文
applied organometallic chemistry, 2008, 卷号: 22, 期号: 6, 页码: 333-340
Song DP; Li YG; Lu R; Hu NH; Li YS
收藏  |  浏览/下载:11/0  |  提交时间:2010/04/14
Half-sandwich metal diselenolate complexes Cp#M(NO)(SePh)(2) (M = Mo or W; Cp# = Cp or MeCp) as ligands. Synthesis of selenolate-bridged heterobimetallic compounds 期刊论文
transition metal chemistry, 2001, 卷号: 26, 期号: 4-5, 页码: 496-499
Jin GX; Herberhold M
收藏  |  浏览/下载:147/26  |  提交时间:2010/11/04


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