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新型复合共沉淀法制备高能量/高功率型锂离子二次电池用5V正极材料LiNi_(0.5)Mn_(1.5)O_4及其电化学性能 期刊论文
物理化学学报, 2014
朱智; 其鲁; 李卫; 廖细英
收藏  |  浏览/下载:6/0  |  提交时间:2015/11/13
Synthesis, characterization, and ethylene polymerization behaviors of late-transition metal complexes coordinated with chlorinated bis(arylimino)pyridine ligand 期刊论文
polymer, 2014, 卷号: 55, 期号: 18, 页码: 4611-4618
Liu, Heng; Wang, Feng; Liu, Li; Jai,Xiang-Yu; Zheng,Wenjie; Guo,Jun; Zhang,Chun-Yu; Bai,Chen-Xi; Hu,Yan-Ming; Zhang,Xue-Quan
收藏  |  浏览/下载:20/0  |  提交时间:2015/10/20
A series of late-transition metal complexes supported with chlorinated bis(arylimino)pyridine ligands [2  Ar = 2  Ar = 2  Ar = 2  Ar = 4-Cl-2  Ar = 4-Br-2  6-(ArN=CCl)(2)C5H3N]MtCl(2) (Ar = 2  6-(Pr2C6H3)-Pr-i  6-Et2C6H3  6-Me2C6H3  6-Me2C6H2  6-Me2C6H2  4  Mt = Fe (1b)  Mt = Co (1c)  Mt = Fe (1d)  Mt = Fe (1e)  Mt = Fe (1f)  6-Me3C6H2  Co (2b)  Ni (3c)  Co (2d)  Co (2e)  Co (2f)) were synthesized. At the presence of methylaluminoxane (MAO)  Mt = Fe (1a)  Fe(II)- and Co(II)- based complexes were highly active towards ethylene polymerization  Co (2a)  affording polymers with bimodal and unimodal molar. mass distributions  Ni (3a)  respectively  while the Ni(II)-based complexes gave no polymer products. Moreover  the obtained polyethylenes were predominately saturated and vinyl-terminated for Fe(II)- and Co(II)-based complexes  respectively. Changing the ligand environment  polymerization parameters also posed a great influence on the catalytic activities and the properties of the resulting polymers. (C) 2014 Elsevier Ltd. All rights reserved.  
Synthesis, characterization, and 1,3-butadiene polymerization studies of Co(II), Ni(II), and Fe(II) complexes bearing 2-(N-arylcarboximidoylchloride)quinoline ligand 期刊论文
journal of molecular catalysis a-chemical, 2014, 卷号: 391, 期号: 52, 页码: 25-35
Liu, Heng; Wang, Feng; Jia, Xiang-Yu; Liu,Li; Bi,Ji-Fu; Zhang,Chun-Yu; Zhao,Li-Ping; Bai,Chen-Xi; Hu,Yan-Ming; Zhang,Xue-Quan
收藏  |  浏览/下载:28/0  |  提交时间:2015/10/20


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