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科研机构
长春应用化学研究所 [1]
内容类型
期刊论文 [1]
发表日期
2014 [1]
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内容类型:期刊论文
专题:长春应用化学研究所
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Synthesis, characterization, and ethylene polymerization behaviors of late-transition metal complexes coordinated with chlorinated bis(arylimino)pyridine ligand
期刊论文
polymer, 2014, 卷号: 55, 期号: 18, 页码: 4611-4618
Liu, Heng
;
Wang, Feng
;
Liu, Li
;
Jai,Xiang-Yu
;
Zheng,Wenjie
;
Guo,Jun
;
Zhang,Chun-Yu
;
Bai,Chen-Xi
;
Hu,Yan-Ming
;
Zhang,Xue-Quan
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浏览/下载:20/0
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提交时间:2015/10/20
A series of late-transition metal complexes supported with chlorinated bis(arylimino)pyridine ligands [2
Ar = 2
Ar = 2
Ar = 2
Ar = 4-Cl-2
Ar = 4-Br-2
6-(ArN=CCl)(2)C5H3N]MtCl(2) (Ar = 2
6-(Pr2C6H3)-Pr-i
6-Et2C6H3
6-Me2C6H3
6-Me2C6H2
6-Me2C6H2
4
Mt = Fe (1b)
Mt = Co (1c)
Mt = Fe (1d)
Mt = Fe (1e)
Mt = Fe (1f)
6-Me3C6H2
Co (2b)
Ni (3c)
Co (2d)
Co (2e)
Co (2f)) were synthesized. At the presence of methylaluminoxane (MAO)
Mt = Fe (1a)
Fe(II)- and Co(II)- based complexes were highly active towards ethylene polymerization
Co (2a)
affording polymers with bimodal and unimodal molar. mass distributions
Ni (3a)
respectively
while the Ni(II)-based complexes gave no polymer products. Moreover
the obtained polyethylenes were predominately saturated and vinyl-terminated for Fe(II)- and Co(II)-based complexes
respectively. Changing the ligand environment
polymerization parameters also posed a great influence on the catalytic activities and the properties of the resulting polymers. (C) 2014 Elsevier Ltd. All rights reserved.
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