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Supramolecular hyperbranched polymers with aggregation-induced emission based on host-enhanced pi-pi interaction for use as aqueous light-harvesting systems 期刊论文
DYES AND PIGMENTS, 2017, 卷号: 146, 页码: 392-397
作者:  Qiao, Fei;  Yuan, Zhao;  Lian, Zhe;  Yan, Chao-Yi;  Zhuo, Shuping
收藏  |  浏览/下载:6/0  |  提交时间:2019/12/11
In this work, we report a simple strategy by mixing a  naphthyl-substituted tetraphenylethylene derivative (TPE) and  cucurbit[8]uril (CB[8]) in aqueous solution based on the hoSt-guest  complexation between CB[8] and TPE  to construct supramolecular  hyperbranched polymers. The host-guest'interaction  between CB[8] and  TPE efficiently restricted the intramolecular rotation and the  non-radiative relaxation channel, thereby resulting in the strong  emission of TPE in dilute solution. We further investigate the  self-assembly behaviors of the obtained supramolecular hyperbranched  polymers in aqueous solution which exhibited individual spherical  aggregates with the diameter of ~60 nm. By using the spherical  aggregates as energy donors and eosin Y disodium salt (EY) as energy  acceptors we have constructed highly efficient aqueous light-harvesting  systems in aqueous solution. (C) 2017 Elsevier Ltd. All rights reserved.  
Fabrication of Propeller-Shaped Supra-amphiphile for Construction of Enzyme-Responsive Fluorescent Vesicles 期刊论文
ACS APPLIED MATERIALS & INTERFACES, 2016
Li, Jie; Liu, Kaerdun; Han, Yuchun; Tang, Ben Zhong; Huang, Jianbin; Yan, Yun
收藏  |  浏览/下载:4/0  |  提交时间:2017/12/03


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