Effect of organic group on modified MSU-X silicate

CORC > 武汉物理与数学研究所 > 中国科学院武汉物理与数学研究所 > 2011年以前论文发表（包括2011年）

	Effect of organic group on modified MSU-X silicate
	Gong, YJ ; Li, ZH ; Wu, D ; Sun, YH ; Deng, F ; Luo, Q ; Yue, Y
刊名	ACTA CHIMICA SINICA
	2001
卷号	59 期号:10 页码:1592-1598
关键词	mesoporous materials organo-functionalized MSU-X interfacial characteristics SAXS characterization
英文摘要	Organo - functionalized MSU - X [R - MSU - X, R = CH3, C6H5, CH2 = CH and NH2CONH(CH2)(3)] silicates were prepared by one - pot synthesis methodology, using an improved procedure developed for synthesizing MSU - X. The incorporated organic groups were characterized by XRD, FT - IR, C-13, Si-29 CP MAS NMR, HRTEM, SEM, TG, N-2 physisorption techniques, bulk element analysis and small angle X ray scattering (SAXS). The surface morphology and textural properties of such materials varied with R groups in organosiloxanes precursor and their content in the pore. The effects of the organic groups on the modified MSU - 1 were investigated carefully. SAXS results show that the organic groups appeared to be uniformly distributed in R - MSU - X and form interfacial layers that led to the scattering of the pore distortion and gave a negative deviation from Porod's law. The average thickness of the interfacial layer was further obtained by analyzing this deviation.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
关键词[WOS]	MESOPOROUS SILICA ; RAY-SCATTERING ; SURFACTANT ; MCM-41
收录类别	SCI
语种	英语
WOS记录号	WOS:000171884400013
公开日期	2015-12-08
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/8638]
专题	武汉物理与数学研究所_2011年以前论文发表（包括2011年）
作者单位	1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China 2.Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom Mol Phys, Wuhan 430071, Peoples R China
推荐引用方式 GB/T 7714	Gong, YJ,Li, ZH,Wu, D,et al. Effect of organic group on modified MSU-X silicate[J]. ACTA CHIMICA SINICA,2001,59(10):1592-1598.
APA	Gong, YJ.,Li, ZH.,Wu, D.,Sun, YH.,Deng, F.,...&Yue, Y.(2001).Effect of organic group on modified MSU-X silicate.ACTA CHIMICA SINICA,59(10),1592-1598.
MLA	Gong, YJ,et al."Effect of organic group on modified MSU-X silicate".ACTA CHIMICA SINICA 59.10(2001):1592-1598.