Synthesis and characterization of novel heteronuclear complexes of Ln(III)-Cu(II) with non-cyclic polyether Schiff base

CORC > 武汉物理与数学研究所 > 中国科学院武汉物理与数学研究所 > 2011年以前论文发表（包括2011年）

	Synthesis and characterization of novel heteronuclear complexes of Ln(III)-Cu(II) with non-cyclic polyether Schiff base
	Yao, KM ; Wu, J ; Xu, Q ; Shen, LF ; Yuan, HZ
刊名	CHINESE JOURNAL OF CHEMISTRY
	1998-09-01
卷号	16 期号:5 页码:430-435
关键词	lanthanide non-cyclic Schiff base heteronuclear complex NMR spectra
英文摘要	Nine novel heteronuclear complexes of Ln(III)-Cu(II) with salicylidene tetraethylene glycol diamine (SALTTA) have been synthesized and characterized. They have the general formulae [LnCu(2)(SALTTA)(2)(NO3)(3)](NO3)(4).3H2O (Ln=La, Pr, Nd, Sm) and [LnCu(3)(SALTTA)(3)(NO3)(5)]- (NO3)(4).4H(2)O (Ln=Gd, Tb, Er, Yb, Y). The III spectra show that v(C=N) in the Ln(III)-Cn(II) heteronuclear complexes are splitted up into two peaks with a far distance. It has been confirmed that oxygen atoms in oxyethylene of the ligand are not all coordinated to the central metal ions by both IR and NMR methods.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
关键词[WOS]	MOLECULAR-STRUCTURE ; CRYSTAL ; COPPER
收录类别	SCI
语种	英语
WOS记录号	WOS:000076768800007
公开日期	2015-12-01
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/8324]
专题	武汉物理与数学研究所_2011年以前论文发表（包括2011年）
作者单位	1.Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China 2.Hangzhou Teachers Coll, Dept Chem, Hangzhou 310012, Zhejiang, Peoples R China 3.Acad Sinica, Wuhan Inst Phys, Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China
推荐引用方式 GB/T 7714	Yao, KM,Wu, J,Xu, Q,et al. Synthesis and characterization of novel heteronuclear complexes of Ln(III)-Cu(II) with non-cyclic polyether Schiff base[J]. CHINESE JOURNAL OF CHEMISTRY,1998,16(5):430-435.
APA	Yao, KM,Wu, J,Xu, Q,Shen, LF,&Yuan, HZ.(1998).Synthesis and characterization of novel heteronuclear complexes of Ln(III)-Cu(II) with non-cyclic polyether Schiff base.CHINESE JOURNAL OF CHEMISTRY,16(5),430-435.
MLA	Yao, KM,et al."Synthesis and characterization of novel heteronuclear complexes of Ln(III)-Cu(II) with non-cyclic polyether Schiff base".CHINESE JOURNAL OF CHEMISTRY 16.5(1998):430-435.