Enantioselective Friedel-Crafts reactions in water catalyzed by a human telomeric G-quadruplex DNA metalloenzyme

	Enantioselective Friedel-Crafts reactions in water catalyzed by a human telomeric G-quadruplex DNA metalloenzyme
	Wang, Changhao 1,2; Li, Yinghao 1,2; Jia, Guoqing 1; Liu, Yan 1; Lu, Shengmei 1; Li, Can 1
刊名	chemical communications
	2012
卷号	48 期号:50 页码:6232-6234
英文摘要	a human telomeric g-quadruplex (g4dna) metalloenzyme, assembled with g4dna and cu2+ ions, can catalyze the enantioselective friedel-crafts (f-c) reaction in water with good enantioselectivity (up to 75% ee). furthermore, we found that the absolute configuration and the enantioselectivity of the product largely depend on the conformation and the sequence of g4dna.
类目[WOS]	chemistry, multidisciplinary
研究领域[WOS]	chemistry
关键词[WOS]	bis(oxazolinyl)pyridine-scandium(iii) triflate complexes ; intramolecular g-quadruplex ; k+ solution ; asymmetric catalysis ; deficient conditions ; alkylation ; sequence ; pyrroles ; forms
收录类别	SCI
语种	英语
WOS记录号	WOS:000304486800007
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/142848]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Wang, Changhao,Li, Yinghao,Jia, Guoqing,et al. Enantioselective Friedel-Crafts reactions in water catalyzed by a human telomeric G-quadruplex DNA metalloenzyme[J]. chemical communications,2012,48(50):6232-6234.
APA	Wang, Changhao,Li, Yinghao,Jia, Guoqing,Liu, Yan,Lu, Shengmei,&Li, Can.(2012).Enantioselective Friedel-Crafts reactions in water catalyzed by a human telomeric G-quadruplex DNA metalloenzyme.chemical communications,48(50),6232-6234.
MLA	Wang, Changhao,et al."Enantioselective Friedel-Crafts reactions in water catalyzed by a human telomeric G-quadruplex DNA metalloenzyme".chemical communications 48.50(2012):6232-6234.