Highly Enantioselective Iridium-Catalyzed Hydrogenation of 2-Benzylquinolines and 2-Functionalized and 2,3-Disubstituted Quinolines

	Highly Enantioselective Iridium-Catalyzed Hydrogenation of 2-Benzylquinolines and 2-Functionalized and 2,3-Disubstituted Quinolines
	Wang, Da-Wei 1; Wang, Xiao-Bing 1; Wang, Duo-Sheng 1; Lu, Sheng-Mei 1; Zhou, Yong-Gui 1,2; Li, Yu-Xue 2
刊名	journal of organic chemistry
	2009-04-03
卷号	74 期号:7 页码:2780-2787
英文摘要	the enantioselective hydrogenation of 2-benzylquinolines and 2-functionalized and 2,3-disubstituted quinolines was developed by using the [ir(cod)cl]2/bisphosphine/i(2) system with up to 96% ee. moreover, mechanistic studies revealed the hydrogenation mechanism of quinoline involves a 1,4-hydride addition, isomerization, and 1,2-hydride addition, and the catalytic active species may be a ir(iii) complex with chloride and iodide.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, organic
研究领域[WOS]	chemistry
关键词[WOS]	asymmetric transfer hydrogenation ; n-iminopyridinium ylides ; ir-f-binaphane ; heteroaromatic-compounds ; homogeneous hydrogenation ; hantzsch esters ; complexes ; ligands ; derivatives ; indoles
收录类别	SCI ; IC ; CCR
语种	英语
WOS记录号	WOS:000264627400018
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/141246]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式 GB/T 7714	Wang, Da-Wei,Wang, Xiao-Bing,Wang, Duo-Sheng,et al. Highly Enantioselective Iridium-Catalyzed Hydrogenation of 2-Benzylquinolines and 2-Functionalized and 2,3-Disubstituted Quinolines[J]. journal of organic chemistry,2009,74(7):2780-2787.
APA	Wang, Da-Wei,Wang, Xiao-Bing,Wang, Duo-Sheng,Lu, Sheng-Mei,Zhou, Yong-Gui,&Li, Yu-Xue.(2009).Highly Enantioselective Iridium-Catalyzed Hydrogenation of 2-Benzylquinolines and 2-Functionalized and 2,3-Disubstituted Quinolines.journal of organic chemistry,74(7),2780-2787.
MLA	Wang, Da-Wei,et al."Highly Enantioselective Iridium-Catalyzed Hydrogenation of 2-Benzylquinolines and 2-Functionalized and 2,3-Disubstituted Quinolines".journal of organic chemistry 74.7(2009):2780-2787.