Reactions of first-row transition metal ions with propargyl alcohol in the gas phase

	Reactions of first-row transition metal ions with propargyl alcohol in the gas phase
	Zhao, X ; Xin, B ; Xing, XP ; Zhang, X ; Wang, GH ; Gao, Z
刊名	rapid communications in mass spectrometry
	2001
卷号	15 期号:15 页码:1317-1321
英文摘要	the gas-phase reactions with propargyl alcohol (ppa) of all the singly charged ions of the first-row transition metals, generated by laser ablation in an external ion source, were studied by fourier transform ion cyclotron resonance mass spectrometry (ft-icrms.). the reactivities of the metal ions change irregularly across the periodic table, and the reactivity of each ion is a function of its electronic configuration and corresponding metal-oxygen (m-o) bond energies. the 10 metal ions were classified into three categories according to their reactivities: sc+, ti+ and v+ are the most reactive ions which react with ppa to give many kinds of oxygen-rich products due to stronger m-o bonds; fe+, co+ and ni+ are less reactive; cr+, mn+, cu+ and zn+ are the most unreactive ions, due to the half and completely occupied valence electronic configurations. the order of reactivity is ti+ > v+ > sc+ > co+ > fe+ approximate to ni+ > zn+ > cr+ approximate to mn+ approximate to cu+. copyright (c) 2001 john wiley & sons, ltd.
WOS标题词	science & technology ; physical sciences ; technology
类目[WOS]	chemistry, analytical ; spectroscopy
研究领域[WOS]	chemistry ; spectroscopy
关键词[WOS]	dissociation ; chemistry ; energies ; fe+ ; co+ ; cu+
收录类别	SCI
语种	英语
WOS记录号	WOS:000170219300013
公开日期	2015-11-10
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/138978]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Mass Spectrometry Ctr, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Zhao, X,Xin, B,Xing, XP,et al. Reactions of first-row transition metal ions with propargyl alcohol in the gas phase[J]. rapid communications in mass spectrometry,2001,15(15):1317-1321.
APA	Zhao, X,Xin, B,Xing, XP,Zhang, X,Wang, GH,&Gao, Z.(2001).Reactions of first-row transition metal ions with propargyl alcohol in the gas phase.rapid communications in mass spectrometry,15(15),1317-1321.
MLA	Zhao, X,et al."Reactions of first-row transition metal ions with propargyl alcohol in the gas phase".rapid communications in mass spectrometry 15.15(2001):1317-1321.