Preparation and structure and performance examination of double-layer LSM/LSM plus YSZ composite electrodes
Lu, ZG; Jiang, Y; Yan, JW; Dong, YL; Zhang, YH
刊名acta physico-chimica sinica
2000-10-01
卷号16期号:10页码:941-947
关键词SOFC composite LSM electrodes double-layer electrodes AC impedance
英文摘要single layer lsm + ysz and double layers lsm/lsm + ysz composite electrodes with varying ysz content in the lsm + ysz layer have been prepared. the electrochemical properties and microstructures of the electrodes were investigated and compared. the electrochemical performance of the single layer lsm +ysz electrodes was improved when a certain amount of ysz was added due to the increase of the: three phase boundaries (tpb) by the addition of ysz, while excessive ysz addition (60%) caused a decrease in performance, because the in-phase resistance of the electrode increased so high, leading to a reduced effective electrode area. the problem was eliminated by a double-layer lsm/lsm + ysz composite electrode, in which a pure lsm layer functioned as a current collector and reduced the in-phase resistance. as a result, both large tpb area and low ohmic resistance were assured in this kind structure. at 1223 k, the double-layer composite electrode with 50 wt. % ysz has the lowest polarization resistance of 0.3 omega .cm(2).
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, physical
研究领域[WOS]chemistry
关键词[WOS]oxide fuel-cell ; cathodes
收录类别SCI
语种英语
WOS记录号WOS:000168532200014
公开日期2015-11-10
内容类型期刊论文
源URL[http://159.226.238.44/handle/321008/138793]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Lu, ZG,Jiang, Y,Yan, JW,et al. Preparation and structure and performance examination of double-layer LSM/LSM plus YSZ composite electrodes[J]. acta physico-chimica sinica,2000,16(10):941-947.
APA Lu, ZG,Jiang, Y,Yan, JW,Dong, YL,&Zhang, YH.(2000).Preparation and structure and performance examination of double-layer LSM/LSM plus YSZ composite electrodes.acta physico-chimica sinica,16(10),941-947.
MLA Lu, ZG,et al."Preparation and structure and performance examination of double-layer LSM/LSM plus YSZ composite electrodes".acta physico-chimica sinica 16.10(2000):941-947.
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