Product rotational polarization in photo-initiated bimolecular reactions A+BC: Dependence on the character of the potential energy surface for different mass combinations

	Product rotational polarization in photo-initiated bimolecular reactions A+BC: Dependence on the character of the potential energy surface for different mass combinations
	Wang, ML; Han, KL; He, GZ
刊名	journal of physical chemistry a
	1998-12-10
卷号	102 期号:50 页码:10204-10210
英文摘要	in cases of light-heavy-light (lhl), light-light-heavy (llh), and light-heavy-heavy (lhh) mass combinations, the product rotational polarization is reported using the quasiclassical trajectory method in the photoinitiated bimolecular reaction a + bc --> ab + c on attractive, mixed, and repulsive surfaces. four polarization-dependent differential cross sections (pddcs) which are sensitive to many photoinitiated bimolecular reaction experiments are presented. furthermore, the dihedral angle distribution p(phi(r)) characterizing the k-k'-j' correlation and the distribution of angle between k and j' p(theta(r)) are discussed. finally, the angular distributions p(theta(r),phi(r)) of product rotational vectors in the form of polar plots in theta(r) and phi(r) are shown.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, physical ; physics, atomic, molecular & chemical
研究领域[WOS]	chemistry ; physics
关键词[WOS]	state-resolved stereodynamics ; chemiluminescent reaction ; angular-correlations ; exchange-reactions ; cross-sections ; alignment ; orientation ; molecules ; distributions ; magnitude
收录类别	SCI
语种	英语
WOS记录号	WOS:000077543700003
公开日期	2015-11-10
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/138465]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Wang, ML,Han, KL,He, GZ. Product rotational polarization in photo-initiated bimolecular reactions A+BC: Dependence on the character of the potential energy surface for different mass combinations[J]. journal of physical chemistry a,1998,102(50):10204-10210.
APA	Wang, ML,Han, KL,&He, GZ.(1998).Product rotational polarization in photo-initiated bimolecular reactions A+BC: Dependence on the character of the potential energy surface for different mass combinations.journal of physical chemistry a,102(50),10204-10210.
MLA	Wang, ML,et al."Product rotational polarization in photo-initiated bimolecular reactions A+BC: Dependence on the character of the potential energy surface for different mass combinations".journal of physical chemistry a 102.50(1998):10204-10210.