High efficient inverted polymer solar cells with different annealing treatment
Xu, Xiaowei1; Zhang, Fujun1; Zhang, Jian2; Wang, Hui3; Zhuo, Zuliang1; Liu, Yang1; Wang, Jian1; Wang, Zixuan1; Xu, Zheng1
刊名materials science & engineering c-materials for biological applications
2012-05-01
卷号32期号:4页码:685-691
关键词Inverted polymer solar cells Annealing treatment P3HT:PCBM Buffer layers
英文摘要inverted polymer solar cells (ipscs) were fabricated with cesium carbonate (cs2co3) modified indium tin oxide (ito) substrates as the electrode and molybdenum trioxide (moo3) modified al as the anode. the cs2co3 dissolved in 2-ethoxyethanol was spin-coated on ito substrates, showing snowflake-like morphology characterized by the scanning electron microscope (sem). the absorption, x-ray diffraction as well as the morphology of the active layer were measured before and after annealing treatment. the ipscs with annealing treatments on the active layers and moo3 layers exhibited the maximum power conversion efficiency (pce) approaching to 2%, with open circuit voltage (v-oc) of 0.57 v. short circuit current density (j(sc)) of 8.8 ma/cm(2) and fill factor (ff) of 38.7%. the performance of ipscs was dramatically decreased by annealing treatment after the deposition of al cathode, which may be due to the diffusion of al atom crossing the moo3 layer forming new channels for charge carrier collection. however, the new channels are not beneficial to the charge carrier collection, which is demonstrated from that the j(sc) of ipscs was evidently decreased from 8.8 to 4.6 ma/cm(2) by annealing treatment after deposition al layer. the annealing treatment after deposition of moo3 could improve the interfacial contact to aid in electron extraction. (c) 2012 elsevier b.v. all rights reserved.
WOS标题词science & technology ; technology
类目[WOS]materials science, biomaterials
研究领域[WOS]materials science
关键词[WOS]poly(3-hexylthiophene) methano-fullerene ; vertical phase-separation ; open-circuit voltage ; photovoltaic devices ; performance ; blends ; morphology ; improvement ; cs2co3 ; layer
收录类别SCI
语种英语
WOS记录号WOS:000303299300010
公开日期2015-11-10
内容类型期刊论文
源URL[http://159.226.238.44/handle/321008/138087]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Beijing Jiaotong Univ, Key Lab Luminescence & Opt Informat, Minist Educ China, Beijing 100044, Peoples R China
2.Dalian Inst Chem Phys CAS, State Key Lab Catalysis, Dalian 116023, Peoples R China
3.Tech Inst Phys & Chem CAS, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China
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GB/T 7714
Xu, Xiaowei,Zhang, Fujun,Zhang, Jian,et al. High efficient inverted polymer solar cells with different annealing treatment[J]. materials science & engineering c-materials for biological applications,2012,32(4):685-691.
APA Xu, Xiaowei.,Zhang, Fujun.,Zhang, Jian.,Wang, Hui.,Zhuo, Zuliang.,...&Xu, Zheng.(2012).High efficient inverted polymer solar cells with different annealing treatment.materials science & engineering c-materials for biological applications,32(4),685-691.
MLA Xu, Xiaowei,et al."High efficient inverted polymer solar cells with different annealing treatment".materials science & engineering c-materials for biological applications 32.4(2012):685-691.
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