A Water-Promoted Mechanism of Alcohol Oxidation on a Au(111) Surface: Understanding the Catalytic Behavior of Bulk Gold | |
Chang, Chun-Ran1,2; Yang, Xiao-Feng1,2,3; Long, Bo1,2; Li, Jun1,2 | |
刊名 | acs catalysis |
2013-08-01 | |
卷号 | 3期号:8页码:1693-1699 |
关键词 | methanol oxidation bulk gold O-2 activation hydroperoxyl water density functional theory |
英文摘要 | to understand the catalytic mechanism of alcohol oxidation with molecular oxygen on bulk metallic gold catalysts, we have systematically studied the oxidative dehydrogenation of methanol on au(111) using density functional theory. it is found that molecular oxygen can be activated via a hydroperoxyl (ooh) intermediate produced by abstracting a hydrogen atom from co-adsorbed methanol or water. interestingly, extra water molecules significantly promote the hydrogen-transfer reactions between ch3oh center dot center dot center dot o-2 and h2o center dot center dot center dot o-2 co-adsorbates, lowering the activation barrier of ooh formation from similar to 0.90 to similar to 0.45 ev. the formed ooh intermediate either directly reacts with methanol to produce formaldehyde or dissociates into adsorbed atomic oxygen and hydroxyl. further calculations demonstrate that the oxidative dehydrogenation of methanol by ooh, atomic oxygen, and hydroxyl is extremely facile with low barriers between 0.06 and 0.30 ev. these results provide an explanation for the activation mechanism of molecular oxygen on bulk gold and reveal a possible pathway for alcohol oxidation with dioxygen. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, physical |
研究领域[WOS] | chemistry |
关键词[WOS] | chemical-vapor-deposition ; transition-metal surfaces ; density-functional theory ; low-temperature oxidation ; selective oxidation ; aerobic oxidation ; co oxidation ; o-2 dissociation ; phase oxidation ; supported gold |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000322852900002 |
公开日期 | 2015-11-10 |
内容类型 | 期刊论文 |
源URL | [http://159.226.238.44/handle/321008/137735] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China 2.Tsinghua Univ, Minist Educ, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Chang, Chun-Ran,Yang, Xiao-Feng,Long, Bo,et al. A Water-Promoted Mechanism of Alcohol Oxidation on a Au(111) Surface: Understanding the Catalytic Behavior of Bulk Gold[J]. acs catalysis,2013,3(8):1693-1699. |
APA | Chang, Chun-Ran,Yang, Xiao-Feng,Long, Bo,&Li, Jun.(2013).A Water-Promoted Mechanism of Alcohol Oxidation on a Au(111) Surface: Understanding the Catalytic Behavior of Bulk Gold.acs catalysis,3(8),1693-1699. |
MLA | Chang, Chun-Ran,et al."A Water-Promoted Mechanism of Alcohol Oxidation on a Au(111) Surface: Understanding the Catalytic Behavior of Bulk Gold".acs catalysis 3.8(2013):1693-1699. |
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