Iridium-catalyzed asymmetric hydrogenation of dibenzo[b,f][1,4]thiazepines

	Iridium-catalyzed asymmetric hydrogenation of dibenzo[b,f][1,4]thiazepines
	Guo, Ran-Ning 1,2; Gao, Kai 1; Ye, Zhi-Shi 1; Shi, Lei 1; Li, Yanqin 2; Zhou, Yong-Gui 1
刊名	pure and applied chemistry
	2013
卷号	85 期号:4 页码:843-849
关键词	asymmetric hydrogenation dibenzothiazepines heterocyclic chemistry iodine iridium
英文摘要	highly enantioselective hydrogenation of substituted dibenzo[b,f][1,4]thiazepines was achieved with up to 96 % ee (enantiomeric excess) using [ir(cod)cl](2)/(r)-synphos complex as catalyst in the presence of iodine. this method provides an efficient access to optically active 11-substituted-10,11-dihydrodibenzo[b,f][1,4]thiazepines.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, multidisciplinary
研究领域[WOS]	chemistry
关键词[WOS]	ir-f-binaphane ; heteroaromatic-compounds ; enantioselective hydrogenation ; quinolines ; complexes ; imines ; derivatives ; chemistry ; ligands ; access
收录类别	SCI
语种	英语
WOS记录号	WOS:000316740300018
公开日期	2015-11-10
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/137683]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Dalian Univ Technol, Dept Chem, Dalian 116012, Peoples R China
推荐引用方式 GB/T 7714	Guo, Ran-Ning,Gao, Kai,Ye, Zhi-Shi,et al. Iridium-catalyzed asymmetric hydrogenation of dibenzo[b,f][1,4]thiazepines[J]. pure and applied chemistry,2013,85(4):843-849.
APA	Guo, Ran-Ning,Gao, Kai,Ye, Zhi-Shi,Shi, Lei,Li, Yanqin,&Zhou, Yong-Gui.(2013).Iridium-catalyzed asymmetric hydrogenation of dibenzo[b,f][1,4]thiazepines.pure and applied chemistry,85(4),843-849.
MLA	Guo, Ran-Ning,et al."Iridium-catalyzed asymmetric hydrogenation of dibenzo[b,f][1,4]thiazepines".pure and applied chemistry 85.4(2013):843-849.