Toughening of polylactide with epoxy-functionalized methyl methacrylate-butadiene copolymer
Hao, Yanping ; Liang, Hongyu ; Bian, Junjia ; Sun,Shulin ; Zhang,Huiliang ; Dong,Lisong
刊名polymer international
2014
卷号63期号:4页码:660-666
关键词IN-SITU COMPATIBILIZATION IMMISCIBLE POLYMER BLENDS STEP REACTIVE EXTRUSION POLY(LACTIC ACID) MECHANICAL-PROPERTIES PHYSICAL-PROPERTIES L-LACTIDE POLY(EPSILON-CAPROLACTONE) PLASTICIZERS MORPHOLOGY
通讯作者zhang,hl
英文摘要glycidyl methacrylate-functionalized methyl methacrylate-butadiene (mb-g-gma) copolymers were prepared via an emulsion polymerization process. these functionalized copolymers were blended with polylactide (pla). dynamic mechanical analysis and differential scanning calorimetry results showed that the addition of mb-g-gma did not result in a marked change in the glass transition temperature of pla. with an increase of mb-g-gma content, the tensile strength of the blends decreased; however, the elongation at break and impact strength increased significantly. from scanning electron micrographs, there was large plastic deformation (shear yielding) in blends subjected to impact tests, which was an important energy-dissipation process and led to a toughened polymer. rheological investigation demonstrated that there was a significant dependence of viscosity on composition. when the mb-g-gma content increased, the viscosity began to increase. (c) 2013 society of chemical industry
收录类别SCI
语种英语
公开日期2015-10-27
内容类型期刊论文
源URL[http://ir.ciac.jl.cn/handle/322003/57418]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
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GB/T 7714
Hao, Yanping,Liang, Hongyu,Bian, Junjia,et al. Toughening of polylactide with epoxy-functionalized methyl methacrylate-butadiene copolymer[J]. polymer international,2014,63(4):660-666.
APA Hao, Yanping,Liang, Hongyu,Bian, Junjia,Sun,Shulin,Zhang,Huiliang,&Dong,Lisong.(2014).Toughening of polylactide with epoxy-functionalized methyl methacrylate-butadiene copolymer.polymer international,63(4),660-666.
MLA Hao, Yanping,et al."Toughening of polylactide with epoxy-functionalized methyl methacrylate-butadiene copolymer".polymer international 63.4(2014):660-666.
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