SrFe0.8Mo0.2O3-delta: Cathode material for intermediate temperature solid oxide fuel cells | |
Meng,Junling ; Liu,Xiaojuan ; Yao,Chuangang ; Han,Lin ; Liang,Qingshuang ; Wu,Xiaojie ; Meng,Jian | |
刊名 | solid state ionics |
2014 | |
卷号 | 260期号:7页码:43-48 |
关键词 | ELECTRICAL BEHAVIOR OXYGEN REDUCTION SRFE1-XMOXO3-DELTA NONSTOICHIOMETRY STABILITY TRANSPORT |
通讯作者 | liu,xj |
英文摘要 | as a mixed oxygen ionic and electronic conductor, srfe0.8mo0.2o3-delta is confirmed to be a good cathode material for intermediate-temperature solid-state fuel cells (it-sofcs). the sample of srfe0.8mo0.2o3-delta is synthesized by a solid-state reaction method. pure cubic srfe0.8mo0.2o3-delta perovskite, with space group of pm-3 m (no. 221) and lattice parameter a = 3.9120(1) angstrom, is determined via powder x-ray rietveld refinements. x-ray photoelectron spectroscopy testifies the existence of mixed oxidation states fe2+/3+/4+ and mo5+/6+ in the crystal. thermogravimetry analysis consistently shows that the srfe0.8mo0.2o3-delta begins to the loss of lattice oxygen at about 450 degrees c, which overlaps to the inflection temperature of the electrical conductivity profile. the maximum electrical conductivity obtained is about 50.20 s cm(-1) at 450 degrees c, and the impedance 0.11 omega cm(2) at 850 degrees c. the performance demonstrates that srfe0.8mo0.2o3-delta is a potential candidate as a cathode material for it-sofcs. (c) 2014 elsevier b.v. all rights reserved. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2015-10-27 |
内容类型 | 期刊论文 |
源URL | [http://ir.ciac.jl.cn/handle/322003/57413] |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Meng,Junling,Liu,Xiaojuan,Yao,Chuangang,et al. SrFe0.8Mo0.2O3-delta: Cathode material for intermediate temperature solid oxide fuel cells[J]. solid state ionics,2014,260(7):43-48. |
APA | Meng,Junling.,Liu,Xiaojuan.,Yao,Chuangang.,Han,Lin.,Liang,Qingshuang.,...&Meng,Jian.(2014).SrFe0.8Mo0.2O3-delta: Cathode material for intermediate temperature solid oxide fuel cells.solid state ionics,260(7),43-48. |
MLA | Meng,Junling,et al."SrFe0.8Mo0.2O3-delta: Cathode material for intermediate temperature solid oxide fuel cells".solid state ionics 260.7(2014):43-48. |
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