Syntheses, Structure, and Properties of Mixed Cp-Amidinate Rare-Earth-Metal(III) Complexes

	Syntheses, Structure, and Properties of Mixed Cp-Amidinate Rare-Earth-Metal(III) Complexes
	Liu, Jun-Feng ; Pan, Fu-Xing ; Yao, Shuang ; Min,Xue ; Cuo,Dongmei ; Sun,Zhong-Ming
刊名	organometallics
	2014
卷号	33 期号:6 页码:1374-1381
关键词	RAY CRYSTAL-STRUCTURE EARTH-METAL COMPLEXES ACTINIDES ANNUAL SURVEY SINGLE-MOLECULE MAGNETS H BOND ACTIVATION ORGANOYTTRIUM HYDRIDE COMPLEXES RING-OPENING POLYMERIZATION ATOMIC LAYER DEPOSITION X-RAY LANTHANIDE COMPLEXES
通讯作者	sun,zm
英文摘要	a family of mixed cp-amidinate rare-earth-metal(iii) complexes [cp(2)l(1)lnphcn] (ln = y (1), la (2), sm (3), eu (4), gd (5), tb (6), dy (7); l-1 = phc-(nsime3)(2)), [cp(2)l(1)ln] (ln = er (8), yb (9)), and [cp(2)l(2)ln] (ln = y (10), eu (11), gd (12), tb (13), dy (14), er (15); l-2 = n(t-bu)c(ph)n(sime3)) were synthesized by treatment of cp(3)ln with lithium amidinates. the phase transition has been observed for compounds 5 and 9 at low temperature (200 k). single-crystal structural analyses reveal that compounds 1, 3, 4, 5b, 6, 7, 9b, and 10-15 contain two staggered cp rings. in contrast, two eclipsed cp rings were observed in compounds 2, 5a, 8, and 9a. moreover, the luminescent properties of complex 6 and magnetic properties of complex 7 were also investigated.
收录类别	SCI
语种	英语
WOS记录号	WOS:000333478400008
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/57207]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Liu, Jun-Feng,Pan, Fu-Xing,Yao, Shuang,et al. Syntheses, Structure, and Properties of Mixed Cp-Amidinate Rare-Earth-Metal(III) Complexes[J]. organometallics,2014,33(6):1374-1381.
APA	Liu, Jun-Feng,Pan, Fu-Xing,Yao, Shuang,Min,Xue,Cuo,Dongmei,&Sun,Zhong-Ming.(2014).Syntheses, Structure, and Properties of Mixed Cp-Amidinate Rare-Earth-Metal(III) Complexes.organometallics,33(6),1374-1381.
MLA	Liu, Jun-Feng,et al."Syntheses, Structure, and Properties of Mixed Cp-Amidinate Rare-Earth-Metal(III) Complexes".organometallics 33.6(2014):1374-1381.