Enhanced Catalytic Performance of Composition-Tunable PtCu Nanowire Networks for Methanol Electrooxidation | |
Xiao, Meiling ; Li, Songtao ; Zhao, Xiao ; Zhu,Jianbing ; Yin,Min ; Liu,Changpeng ; Xing,Wei | |
刊名 | chemcatchem |
2014 | |
卷号 | 6期号:10页码:2825-2831 |
关键词 | OXYGEN REDUCTION REACTION HIGH-INDEX FACETS FUEL-CELLS ELECTROCATALYTIC PERFORMANCE OXIDATION NANOCUBES CU NANOCRYSTALS ELECTROLYTE NANOPARTICLES |
通讯作者 | liu,cp |
英文摘要 | ultrathin ptcux (x=1, 2 and 3) nanowire networks (nwms) with controllable compositions were successfully synthesized by using triton x-100 as the structure-directing agent in aqueous solution. the as-prepared ptcux nanocrystals were characterized by transmission electron microscopy, x-ray diffraction, x-ray photoelectron spectroscopy, cyclic voltammetry, and chronoamperometry. the results show that electrocatalytic performance of the ptcux nwns towards the methanol oxidation reaction is enhanced relative to that of commercial pt/c catalysts. moreover, if the initial atomic ratio of pt/cu is 1:2, the corresponding ptcu2 nwns catalyst generates mass activity that is 3.77-fold higher and specific activity that is 2.71-fold higher than the corresponding properties of commercial pt/c catalysts. the enhanced activity can be attributed to a unique structure and a modified electronic effect. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2015-10-27 |
内容类型 | 期刊论文 |
源URL | [http://ir.ciac.jl.cn/handle/322003/56245] |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Xiao, Meiling,Li, Songtao,Zhao, Xiao,et al. Enhanced Catalytic Performance of Composition-Tunable PtCu Nanowire Networks for Methanol Electrooxidation[J]. chemcatchem,2014,6(10):2825-2831. |
APA | Xiao, Meiling.,Li, Songtao.,Zhao, Xiao.,Zhu,Jianbing.,Yin,Min.,...&Xing,Wei.(2014).Enhanced Catalytic Performance of Composition-Tunable PtCu Nanowire Networks for Methanol Electrooxidation.chemcatchem,6(10),2825-2831. |
MLA | Xiao, Meiling,et al."Enhanced Catalytic Performance of Composition-Tunable PtCu Nanowire Networks for Methanol Electrooxidation".chemcatchem 6.10(2014):2825-2831. |
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