Oxazoline and Imidazoline Functionalization of a C-60 Dimer via the Reaction of C60HBn and Aromatic Nitriles with a Bifunctional Hydroxide

	Oxazoline and Imidazoline Functionalization of a C-60 Dimer via the Reaction of C60HBn and Aromatic Nitriles with a Bifunctional Hydroxide
	Li,Zong-Jun ; Li,Shu-Hui ; Sun,Tao ; Gao,Xiang
刊名	journal of organic chemistry
	2014
卷号	79 期号:1 页码:197-203
关键词	FULLERENE DIMER 2+2 CYCLOADDITION DERIVATIVES C-120 FULLEROOXAZOLES ADDUCT R3C60 NMR
通讯作者	gao,x
英文摘要	oxazoline and imidazoline functionalization of a singly bonded c-60 dimer is achieved via a one-pot reaction of c60hbn with oh- and aromatic nitriles, where the oh- not only functions as a bronsted base that deprotonates c60hbn but also as a nucleophile that initiates the nucleophilic addition to the fullerene cage. the structures of the obtained oxazolinated and imidazolinated c-60 dimeric compounds have been established by hrms, uv-vis, and h-1, c-13, and hmbc nmr characterizations and computational calculations. the reaction mechanism is studied with the in situ vis-near-ir spectra, which shows that the use of i-2 is crucial for the functionalization of the c-60 dimer, indicating that it is likely the dimeric molecule rather than the fragment of the dimer that is involved in the reaction.
收录类别	SCI
语种	英语
公开日期	2015-10-27
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/56222]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Li,Zong-Jun,Li,Shu-Hui,Sun,Tao,et al. Oxazoline and Imidazoline Functionalization of a C-60 Dimer via the Reaction of C60HBn and Aromatic Nitriles with a Bifunctional Hydroxide[J]. journal of organic chemistry,2014,79(1):197-203.
APA	Li,Zong-Jun,Li,Shu-Hui,Sun,Tao,&Gao,Xiang.(2014).Oxazoline and Imidazoline Functionalization of a C-60 Dimer via the Reaction of C60HBn and Aromatic Nitriles with a Bifunctional Hydroxide.journal of organic chemistry,79(1),197-203.
MLA	Li,Zong-Jun,et al."Oxazoline and Imidazoline Functionalization of a C-60 Dimer via the Reaction of C60HBn and Aromatic Nitriles with a Bifunctional Hydroxide".journal of organic chemistry 79.1(2014):197-203.