Multifunctional Antireflection Coatings Based on Novel Hollow Silica-Silica Nanocomposites
Zhang, Xianpeng ; Lan, Pinjun ; Lu, Yuehui ; Li, Jia ; Xu, Hua ; Zhang, Jing ; Lee, YoungPak ; Rhee, Joo Yull ; Choy, Kwang-Leong ; Song, Weijie
刊名ACS APPLIED MATERIALS & INTERFACES
2014
卷号6期号:3页码:1415
中文摘要Antireflection (AR) coatings that exhibit multifunctional characteristics, including high transparency, robust resistance to moisture, high hardness, and antifogging properties, were developed based on hollow silica-silica nanocomposites. These novel nanocomposite coatings with a closed-pore structure, consisting of hollow silica nanospheres (HSNs) infiltrated with an acid-catalyzed silica sol (ACSS), were fabricated using a low-cost sot gel dip-coating method. The refractive index of the nanocomposite coatings was tailored by controlling the amount of ACSS infiltrated into the HSNs during synthesis. Photovoltaic transmittance (T-PV) values of 96.86-97.34% were obtained over a broad range of wavelengths, from 300 to 1200 nm; these values were close to the theoretical limit for a lossy single-layered AR coating (97.72%). The nanocomposite coatings displayed a stable T-PV, with degradation values of less than 4% and 0.1% after highly accelerated temperature and humidity stress tests, and abrasion tests, respectively. In addition, the nanocomposite coatings had a hardness of approximately 1.6 GPa, while the porous silica coatings with an open-pore structure showed more severe degradation and had a lower hardness. The void fraction and surface roughness of the nanocomposite coatings could be controlled, which gave rise to near-superhydrophilic and antifogging characteristics. The promising results obtained in this study suggest that the nanocomposite coatings have the potential to be of benefit for the design, fabrication, and development of multifunctional AR coatings with both omnidirectional broadband transmission and long-term durability that are required for demanding outdoor applications in energy harvesting and optical instrumentation in extreme climates or humid conditions.
公开日期2015-09-20
内容类型期刊论文
源URL[http://ir.nimte.ac.cn/handle/174433/11934]  
专题宁波材料技术与工程研究所_2014专题
推荐引用方式
GB/T 7714
Zhang, Xianpeng,Lan, Pinjun,Lu, Yuehui,et al. Multifunctional Antireflection Coatings Based on Novel Hollow Silica-Silica Nanocomposites[J]. ACS APPLIED MATERIALS & INTERFACES,2014,6(3):1415.
APA Zhang, Xianpeng.,Lan, Pinjun.,Lu, Yuehui.,Li, Jia.,Xu, Hua.,...&Song, Weijie.(2014).Multifunctional Antireflection Coatings Based on Novel Hollow Silica-Silica Nanocomposites.ACS APPLIED MATERIALS & INTERFACES,6(3),1415.
MLA Zhang, Xianpeng,et al."Multifunctional Antireflection Coatings Based on Novel Hollow Silica-Silica Nanocomposites".ACS APPLIED MATERIALS & INTERFACES 6.3(2014):1415.
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