Solid-state NMR studies of methanol-to-aromatics reaction over silver exchanged HZSM-5 zeolite
Zeng, Danfin; Yang, Jun; Wang, Jiqing; Xu, Jun; Yang, Yongxia; Ye, Chaohui; Deng, Feng
刊名MICROPOROUS AND MESOPOROUS MATERIALS
2007-01-05
卷号98期号:1-3页码:214-219
关键词methanol conversion to aromatics AgZSM-5 solid-state NMR
英文摘要Solid-state NMR spectroscopy was used to study the conversion of methanol to aromatics (MTA) over silver exchanged HZSM-5 zeolites. It is the silver oxide rather than silver cation that plays a crucial role for the MTA reaction. The aromatic products (mainly toluene and benzene) are formed at the expense of the small alkanes (mainly propane and isobutane). AgZSM-5 zeolite calcined in air shows much higher activity and selectivity for the MTA conversion compared with AgZSM-5 zeolite calcined in vacuum or HZSM-5 zeolite. A possible reaction mechanism is proposed for the MTA conversion on the AgZSM-5 zeolite. (C) 2006 Elsevier Inc. All rights reserved.
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
研究领域[WOS]Chemistry ; Science & Technology - Other Topics ; Materials Science
关键词[WOS]XE-129 CHEMICAL-SHIFTS ; BRONSTED ACID SITES ; CARBON-CARBON BOND ; IN-SITU ; HETEROGENEOUS CATALYSIS ; REACTION-MECHANISM ; OLEFIN CATALYSIS ; SELECTIVE CONVERSION ; REACTION PATHWAYS ; DIMETHYL ETHER
收录类别SCI
语种英语
WOS记录号WOS:000243695000028
公开日期2015-09-08
内容类型期刊论文
源URL[http://ir.wipm.ac.cn/handle/112942/7797]  
专题武汉物理与数学研究所_2011年以前论文发表(包括2011年)
作者单位Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China
推荐引用方式
GB/T 7714
Zeng, Danfin,Yang, Jun,Wang, Jiqing,et al. Solid-state NMR studies of methanol-to-aromatics reaction over silver exchanged HZSM-5 zeolite[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2007,98(1-3):214-219.
APA Zeng, Danfin.,Yang, Jun.,Wang, Jiqing.,Xu, Jun.,Yang, Yongxia.,...&Deng, Feng.(2007).Solid-state NMR studies of methanol-to-aromatics reaction over silver exchanged HZSM-5 zeolite.MICROPOROUS AND MESOPOROUS MATERIALS,98(1-3),214-219.
MLA Zeng, Danfin,et al."Solid-state NMR studies of methanol-to-aromatics reaction over silver exchanged HZSM-5 zeolite".MICROPOROUS AND MESOPOROUS MATERIALS 98.1-3(2007):214-219.
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