Targeted synthesis of an electroactive organic framework

CORC > 武汉物理与数学研究所 > 中国科学院武汉物理与数学研究所 > 2011年以前论文发表（包括2011年）

	Targeted synthesis of an electroactive organic framework
	Ben, Teng 3; Shi, Kang 1,2; Cui, Yan 3; Pei, Cuiying 3; Zuo, Yang 1,2; Guo, Han 3; Zhang, Daliang 3; Xu, Jun 4; Deng, Feng 4; Tian, Zhongqun 1,2
刊名	JOURNAL OF MATERIALS CHEMISTRY
	2011
卷号	21 期号:45 页码:18208-18214
产权排序	第一
英文摘要	A new strategy for targeted design and synthesis of an electroactive microporous organic molecular sieve (JUC-Z2) is described. Experiment demonstrated that such a targeted synthesis approach to achieve phenyl-phenyl coupling was a controllable process and predominately generated two-dimensional polymer sheets, significantly different from the traditional chemical or electrochemical oxidation methods to prepare conducting polymers. Successive self-assembly leads to a lamellar organic framework comprised of stacked polymer sheets with an hcb topology. JUC-Z2 was found to have a well-defined uniform micropore distribution (similar to 1.2 nm), a large surface area (BET = 2081 m(2) g(-1)) and high physicochemical stability (> 440 degrees C). After doping with I(2), JUC-Z2 exhibits typical p-type semiconductive properties. As the first example of an electroactive organic framework, JUC-Z2 possesses a unique ability of electrochemical ion recognition, arising from the synergistic function of the uniform micropores and the N-atom redox site.
学科主题	波谱学
WOS标题词	Science & Technology ; Physical Sciences ; Technology
类目[WOS]	Chemistry, Physical ; Materials Science, Multidisciplinary
研究领域[WOS]	Chemistry ; Materials Science
关键词[WOS]	HIGH-SURFACE-AREA ; CONJUGATED MICROPOROUS POLYMERS ; ELECTROLUMINESCENT DEVICES ; HETEROGENEOUS CATALYSIS ; HYDROGEN STORAGE ; NETWORKS ; POLYANILINE ; DESIGN ; CRYSTALLINE ; TEMPLATES
收录类别	SCI
语种	英语
WOS记录号	WOS:000296735900012
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/1894]
专题	武汉物理与数学研究所_2011年以前论文发表（包括2011年）
作者单位	1.Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 2.Xiamen Univ, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China 3.Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China 4.Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan, Peoples R China
推荐引用方式 GB/T 7714	Ben, Teng,Shi, Kang,Cui, Yan,et al. Targeted synthesis of an electroactive organic framework[J]. JOURNAL OF MATERIALS CHEMISTRY,2011,21(45):18208-18214.
APA	Ben, Teng.,Shi, Kang.,Cui, Yan.,Pei, Cuiying.,Zuo, Yang.,...&Qiu, Shilun.(2011).Targeted synthesis of an electroactive organic framework.JOURNAL OF MATERIALS CHEMISTRY,21(45),18208-18214.
MLA	Ben, Teng,et al."Targeted synthesis of an electroactive organic framework".JOURNAL OF MATERIALS CHEMISTRY 21.45(2011):18208-18214.