Selected cis- and trans-p-methoxystyrene rotamers studied by mass-analyzed threshold ionization spectroscopy

CORC > 武汉物理与数学研究所 > 中国科学院武汉物理与数学研究所 > 2011年以前论文发表（包括2011年）

	Selected cis- and trans-p-methoxystyrene rotamers studied by mass-analyzed threshold ionization spectroscopy
	Qin, Chaochao 1,2,3,4; Tzeng, Sheng Yuan 1,2; Zhang, Bing 3; Tzeng, Wen Bih 1,2
刊名	CHEMICAL PHYSICS LETTERS
	2011-02-08
卷号	503 期号:1-3 页码:25-28
通讯作者	Tzeng,WB
产权排序	第三
英文摘要	We applied the two-color resonant two-photon ionization and mass-analyzed threshold ionization techniques to investigate the ionic properties of the selected rotamers of p-methoxystyrene. The adiabatic ionization energies of cis- and trans-p-methoxystyrene are determined to be 62 487 +/- 5 and 62 512 +/- 5 cm (1), respectively. Most of the observed active vibrations involve in-plane ring and substituent-sensitive motions. Our experimental results show that different orientation of the methoxyl group with respect to the vinyl group only slightly influence these cation vibrations, depending on the degree of involvement of the substituents involved in the overall vibrations. (C) 2011 Elsevier B. V. All rights reserved.
学科主题	原子分子物理学
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
研究领域[WOS]	Chemistry ; Physics
关键词[WOS]	ROTATIONAL ISOMERS ; CATION ; ENERGY ; ZEKE ; FLUORESCENCE ; DYNAMICS ; JET
收录类别	SCI
语种	英语
WOS记录号	WOS:000286976700004
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/1819]
专题	武汉物理与数学研究所_2011年以前论文发表（包括2011年）
作者单位	1.Acad Sinica, Inst Atom & Mol Sci, Taipei 10617, Taiwan 2.Natl Taiwan Normal Univ, Dept Chem, Taipei 11677, Taiwan 3.Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China 4.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Qin, Chaochao,Tzeng, Sheng Yuan,Zhang, Bing,et al. Selected cis- and trans-p-methoxystyrene rotamers studied by mass-analyzed threshold ionization spectroscopy[J]. CHEMICAL PHYSICS LETTERS,2011,503(1-3):25-28.
APA	Qin, Chaochao,Tzeng, Sheng Yuan,Zhang, Bing,&Tzeng, Wen Bih.(2011).Selected cis- and trans-p-methoxystyrene rotamers studied by mass-analyzed threshold ionization spectroscopy.CHEMICAL PHYSICS LETTERS,503(1-3),25-28.
MLA	Qin, Chaochao,et al."Selected cis- and trans-p-methoxystyrene rotamers studied by mass-analyzed threshold ionization spectroscopy".CHEMICAL PHYSICS LETTERS 503.1-3(2011):25-28.