A new class of ion-ion interaction: Z-bond

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	A new class of ion-ion interaction: Z-bond
	Dong, Kun ; Zhang, Suojiang 1; Wang, Qian
刊名	SCIENCE CHINA-CHEMISTRY
	2015-03-01
卷号	58 期号:3 页码:495-500
关键词	ionic liquid interaction hydrogen bond Z-bond
ISSN号	1674-7291
通讯作者	Zhang, SJ (reprint author), Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China.
英文摘要	The hydrogen-bond interactions in ionic liquids have been simply described by the conventional hydrogen-bond model of A-Ha <-B. Coupling with the strong electrostatic force, however, hydrogen bond between the cation and anion shows particular features in the geometric, energetic, electronic, and dynamic aspects, which is inherently different from that of the conventional hydrogen bond. A general model could be expressed as (+)[A-Ha <-B](-), in which A and B represent heavy atoms and "+" and "-aEuroe represent the charges of the cation containing A atom and anion containing B atom, respectively. Because the structure shows a "zig-zag" motif, this coupling interaction is defined here as the Z-bond. The new model could be generally used to describe the interactions in ionic liquids, as well as bio-systems involved in ions, ionic reaction, and ionic materials.
学科主题	Chemistry
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
关键词[WOS]	HYDROGEN-BONDS ; SOLID-STATE ; LIQUIDS ; SALTS ; SPECTROSCOPY ; COMPLEXES ; CHLORIDE
收录类别	SCI
语种	英语
WOS记录号	WOS:000350336500020
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/13822]
专题	过程工程研究所_研究所（批量导入）
作者单位	1.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Dong, Kun,Zhang, Suojiang,Wang, Qian. A new class of ion-ion interaction: Z-bond[J]. SCIENCE CHINA-CHEMISTRY,2015,58(3):495-500.
APA	Dong, Kun,Zhang, Suojiang,&Wang, Qian.(2015).A new class of ion-ion interaction: Z-bond.SCIENCE CHINA-CHEMISTRY,58(3),495-500.
MLA	Dong, Kun,et al."A new class of ion-ion interaction: Z-bond".SCIENCE CHINA-CHEMISTRY 58.3(2015):495-500.