Carboxylation of terminal alkynes at ambient CO2 pressure in ethylene carbonate

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	Carboxylation of terminal alkynes at ambient CO2 pressure in ethylene carbonate
	Yu, Bing 1,2; Diao, Zhen-Feng 1,2; Guo, Chun-Xiang 1,2; Zhong, Chun-Lai 1,2; He, Liang-Nian 1,2; Zhao, Ya-Nan 1,2; Song, Qing-Wen 1,2; Liu, An-Hua 1,2; Wang, Jin-Quan 3
刊名	GREEN CHEMISTRY
	2013
卷号	15 期号:9 页码:2401-2407
英文摘要	The CuI-catalyzed carboxylation of terminal alkynes with CO2 and alkyl halides using ethylene carbonate as the solvent under mild conditions was studied. DFT calculations reveal that the energy barrier for CO2 insertion into the sp-hybridized Cu-C bond could be reduced by employing ethylene carbonate as the solvent. Notably, the procedure was conducted under ambient CO2 pressure without any external ligands. A broad range of substrates with electron-withdrawing groups or electron-donating groups gave the corresponding products in reasonable yields.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
关键词[WOS]	C-H BONDS ; METAL-CATALYZED CARBOXYLATION ; CARBENE COPPER(I) COMPLEXES ; ALKENYLBORONIC ESTERS ; ORGANIC CARBONATES ; DIMETHYL CARBONATE ; CYCLIC CARBONATES ; FRIENDLY SOLVENT ; ALLYL STANNANES ; DIOXIDE
收录类别	SCI
语种	英语
WOS记录号	WOS:000323179000014
公开日期	2015-05-27
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/13461]
专题	过程工程研究所_研究所（批量导入）
作者单位	1.Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China 2.Nankai Univ, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Yu, Bing,Diao, Zhen-Feng,Guo, Chun-Xiang,et al. Carboxylation of terminal alkynes at ambient CO2 pressure in ethylene carbonate[J]. GREEN CHEMISTRY,2013,15(9):2401-2407.
APA	Yu, Bing.,Diao, Zhen-Feng.,Guo, Chun-Xiang.,Zhong, Chun-Lai.,He, Liang-Nian.,...&Wang, Jin-Quan.(2013).Carboxylation of terminal alkynes at ambient CO2 pressure in ethylene carbonate.GREEN CHEMISTRY,15(9),2401-2407.
MLA	Yu, Bing,et al."Carboxylation of terminal alkynes at ambient CO2 pressure in ethylene carbonate".GREEN CHEMISTRY 15.9(2013):2401-2407.