Nanocarbon-dependent synthesis of one-dimensional bead-chain-like beta-SiC
Zhao, Bin1; Yang, Biyun1; Wang, Tingyu1; Sun, Dongfeng1; Hu, Yongzhen1; Li, Ruixing1; Yin, Shu2; Li, Junping3; Feng, Zhihai3; Duan, Huiping1
刊名POWDER TECHNOLOGY
2013-09-01
卷号246期号:0页码:487-491
关键词beta-SiC Crystal morphology Amorphous materials Nanocarbon Carbothermal reduction
英文摘要Thermodynamically, SiO2 should react with carbon to form CO and SiC at and above a temperature of 1515 degrees C. However, this reaction is incomplete at 1550 degrees C, even with the use of metastable reactants, such as amorphous SiO2 and active carbon powders. In contrast, complete decomposition of SiO2 is achieved at 1450 degrees C using nanocarbon powders instead of active carbon. Additionally, to clarify the effects of size and morphology of SiO2 on the SiC product, we synthesized different SiO2 precursors. Experimental results reveal that the effects of porous SiO2 on both the size and morphology of SiC particles are evident, but not a decrease in carbothermal reduction temperature. Nanocarbon powders reduce the temperature required for the reaction and also strongly affect the transformation kinetics. (c) 2013 Elsevier B.V. All rights reserved.
WOS标题词Science & Technology ; Technology
类目[WOS]Engineering, Chemical
研究领域[WOS]Engineering
关键词[WOS]SILICON-CARBIDE NANORODS ; CARBOTHERMAL REDUCTION ; DIAMOND
收录类别SCI
语种英语
WOS记录号WOS:000324083000055
公开日期2015-05-27
内容类型期刊论文
源URL[http://ir.ipe.ac.cn/handle/122111/13455]  
专题过程工程研究所_研究所(批量导入)
作者单位1.Beihang Univ, Sch Mat Sci & Engn, Minist Educ, Key Lab Aerosp Mat & Performance, Beijing 100191, Peoples R China
2.Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Aoba Ku, Sendai, Miyagi 9808577, Japan
3.Aerosp Res Inst Mat & Proc Technol, Beijing 100076, Peoples R China
4.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Zhao, Bin,Yang, Biyun,Wang, Tingyu,et al. Nanocarbon-dependent synthesis of one-dimensional bead-chain-like beta-SiC[J]. POWDER TECHNOLOGY,2013,246(0):487-491.
APA Zhao, Bin.,Yang, Biyun.,Wang, Tingyu.,Sun, Dongfeng.,Hu, Yongzhen.,...&Sato, Tsugio.(2013).Nanocarbon-dependent synthesis of one-dimensional bead-chain-like beta-SiC.POWDER TECHNOLOGY,246(0),487-491.
MLA Zhao, Bin,et al."Nanocarbon-dependent synthesis of one-dimensional bead-chain-like beta-SiC".POWDER TECHNOLOGY 246.0(2013):487-491.
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