A New Process for Fuel Ethanol Dehydration Based on Modeling the Phase Equilibria of the Anhydrous MgCl2 + Ethanol plus Water System

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	A New Process for Fuel Ethanol Dehydration Based on Modeling the Phase Equilibria of the Anhydrous MgCl2 + Ethanol plus Water System
	Zeng, L. M.; Li, Z. B.
刊名	Aiche Journal
	2015
期号	2 页码:664-676
关键词	fuel ethanol anhydrous magnesium chloride salt extractive distillation vapor-liquor-equilibrium thermodynamic modeling VAPOR-LIQUID-EQUILIBRIA EXTRACTIVE DISTILLATION PROCESS ACTIVITY-COEFFICIENTS AQUEOUS-SOLUTIONS ATMOSPHERIC-PRESSURE TRANSPORT-PROPERTIES ENERGY OPTIMIZATION ELECTROLYTE SYSTEMS FERMENTATION BROTH WATER MIXTURES
其他题名	Aiche J.
中文摘要	The use of ethanol as a fuel for motor engines has attracted significant attention because of its possible environmental and economic advantages over fossil fuel. However, the energy demand for the ethanol dehydration process significantly impacts its production cost. A new and energy efficient process is developed on the basis of salt extractive distillation, which uses recycled MgCl2 granules as a separating agent. Vapor-liquor-equilibria (VLE) data for the ternary MgCl2+ethanol+water system, and the three constituent binary systems were measured at 30, 60, 90, and 101.3 kPa. A large enhancement of relative volatility of the ethanol+water system in the presence of MgCl2 is observed throughout the entire ethanol concentration range, which completely broke the azeotrope. The salt effect of MgCl2 is thought to be the result of energetic interactions and the hydration equilibrium reaction of the Mg2+ ion with water molecules. The calculation results by the mixed-solvent electrolyte model embedded in the OLI platform equipped with new model interaction parameters and equilibrium constant (obtained via the regression of experimental VLE data), provided for a satisfactory means of simulating the MgCl2 salt extractive distillation process. Finally, the process was proven feasible at the laboratory-scale resulting in large granules of recovered MgCl2 and a product of 99.5 wt % ethanol. (c) 2014 American Institute of Chemical Engineers AIChE J, 61: 664-676, 2015
原文出处	://WOS:000348033200024
语种	英语
公开日期	2015-04-01
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/11881]
专题	过程工程研究所_研究所（批量导入）
推荐引用方式 GB/T 7714	Zeng, L. M.,Li, Z. B.. A New Process for Fuel Ethanol Dehydration Based on Modeling the Phase Equilibria of the Anhydrous MgCl2 + Ethanol plus Water System[J]. Aiche Journal,2015(2):664-676.
APA	Zeng, L. M.,&Li, Z. B..(2015).A New Process for Fuel Ethanol Dehydration Based on Modeling the Phase Equilibria of the Anhydrous MgCl2 + Ethanol plus Water System.Aiche Journal(2),664-676.
MLA	Zeng, L. M.,et al."A New Process for Fuel Ethanol Dehydration Based on Modeling the Phase Equilibria of the Anhydrous MgCl2 + Ethanol plus Water System".Aiche Journal .2(2015):664-676.