Two novel macrocyclic organotin(IV) carboxylates based on amide carboxylic acids

CORC > 长春光学精密机械与物理研究所 > 中国科学院长春光学精密机械与物理研究所 > 中科院长春光机所知识产出

	Two novel macrocyclic organotin(IV) carboxylates based on amide carboxylic acids
	Xiao X. ; Yan L. S. ; Mei Z. M. ; Zhu D. S. ; Xu L.
刊名	Rsc Advances
	2014
卷号	4 期号:6 页码:3096-3101
ISSN号	ISBN/2046-2069
英文摘要	Two novel macrocyclic organotin(IV) carboxylates [(n-Bu2Sn)L-1](2)center dot C7H8 (1) (L-1 = 2-(4-carboxyphenylcarbamoyl) benzoic acid) and [(n-Bu2Sn)L-2](3)center dot H2O (2) (L-2 = 5-(1,3-dioxo-1,3-dihydro-isoindol-2-yl)isophthalic acid) were generated by the reactions of dibutyltin oxide with amide dicarboxylic acids and characterized by elemental analysis, IR, H-1 and C-13 NMR spectroscopy. X-ray crystallography diffraction analyses reveal that 1 is a di-nuclear dicarboxylate ring and 2 is a trinuclear tricarboxylate macrocycle. With the help of intermolecular interactions, 1 and 2 construct supramolecular 3D architectures filled with cavities. Free toluene and water molecules are located in the cavities of 1 and 2 respectively as guests. Thermal analyses suggest that complex 2 is thermally more stable than 1. The antitumour activity of 1 and 2 has also been studied.
收录类别	SCI ; EI
语种	英语
内容类型	期刊论文
源URL	[http://ir.ciomp.ac.cn/handle/181722/44492]
专题	长春光学精密机械与物理研究所_中科院长春光机所知识产出
推荐引用方式 GB/T 7714	Xiao X.,Yan L. S.,Mei Z. M.,et al. Two novel macrocyclic organotin(IV) carboxylates based on amide carboxylic acids[J]. Rsc Advances,2014,4(6):3096-3101.
APA	Xiao X.,Yan L. S.,Mei Z. M.,Zhu D. S.,&Xu L..(2014).Two novel macrocyclic organotin(IV) carboxylates based on amide carboxylic acids.Rsc Advances,4(6),3096-3101.
MLA	Xiao X.,et al."Two novel macrocyclic organotin(IV) carboxylates based on amide carboxylic acids".Rsc Advances 4.6(2014):3096-3101.