Cooperative downconversion and near infrared luminescence of Tm3+/Yb3+ codoped Calcium Scandate phosphor

CORC > 长春光学精密机械与物理研究所 > 中国科学院长春光学精密机械与物理研究所 > 中科院长春光机所知识产出

	Cooperative downconversion and near infrared luminescence of Tm3+/Yb3+ codoped Calcium Scandate phosphor
	Li J. ; Zhang J. H. ; Zhang X. ; Hao Z. D. ; Luo Y. S.
刊名	Journal of Alloys and Compounds
	2014
期号	583 页码:96-99
ISSN号	ISBN/0925-8388
英文摘要	An efficient near infrared (NIR) quantum cutting in CaSc2O4: Tm3+/Yb3+ phosphor has been demonstrated by the visible and NIR spectra properties as well as the decay curves of Tm3+: (1)G(4) level. Upon excitation of Tm3+: (1)G(4) level with a blue photon at 466 nm, Yb3+: F-2(5/2) level can emit two NIR photons around 1000 nm through cooperative energy transfer (ET) from Tm3+ to Yb3+ with the maximum energy transfer efficiency is 71%, and highest theoretical quantum efficiency reaches 171%, close to the limit of 200%. Because the energy of Yb3+ transition is matched well with band gap of crystalline silicon, the excellent downconversion luminescence property indicates that CaSc2O4: Tm3+/Yb3+ is a promising oxide material for increasing the conversion efficiency of crystalline silicon solar cells. (C) 2013 Elsevier Ltd. All rights reserved.
收录类别	SCI ; EI
语种	英语
内容类型	期刊论文
源URL	[http://ir.ciomp.ac.cn/handle/181722/43810]
专题	长春光学精密机械与物理研究所_中科院长春光机所知识产出
推荐引用方式 GB/T 7714	Li J.,Zhang J. H.,Zhang X.,et al. Cooperative downconversion and near infrared luminescence of Tm3+/Yb3+ codoped Calcium Scandate phosphor[J]. Journal of Alloys and Compounds,2014(583):96-99.
APA	Li J.,Zhang J. H.,Zhang X.,Hao Z. D.,&Luo Y. S..(2014).Cooperative downconversion and near infrared luminescence of Tm3+/Yb3+ codoped Calcium Scandate phosphor.Journal of Alloys and Compounds(583),96-99.
MLA	Li J.,et al."Cooperative downconversion and near infrared luminescence of Tm3+/Yb3+ codoped Calcium Scandate phosphor".Journal of Alloys and Compounds .583(2014):96-99.