Controlled self-assembly of alkylated-pi compounds for soft materials - Towards optical and optoelectronic applications

CORC > 兰州化学物理研究所 > 中国科学院兰州化学物理研究所 > 清洁能源化学与材料实验室

	Controlled self-assembly of alkylated-pi compounds for soft materials - Towards optical and optoelectronic applications
	Agnieszka Zielinska 1,2; Marcin Leonowicz 2; Li HG(李洪光)3 ; Takashi Nakanishi 1,2
刊名	Current Opinion in Colloid and Interface Science
	2014
卷号	19 期号:2 页码:131-139
关键词	Alkyl chains Hydrophobic amphiphiles Organic electronics pi-Conjugated compounds Self-assembly
ISSN号	1359-0294
通讯作者	李洪光 ; Takashi Nakanishi
英文摘要	Organic and polymeric molecules based on pi-conjugated units represent an important class of components for optical and optoelectronic functionalized soft materials. Inspired by the innovative molecular design made by synthetic chemists, new functions and applications of pi-conjugated molecules are continuously emerging. However, a challenge that remains is to soften these molecules. Alkylation is a commonly employed synthetic strategy to achieve functionalization in order to improve processability, i.e., solubility in volatile solvents, for better utilization in the rapidly-developing field of organic electronics. In addition it is recognized as a powerful strategy to tune the interaction among the pi-conjugated moieties. In a different interpretation of alkylation, alkylated-pi compounds can be viewed as a class of hydrophobic amphiphiles, since the rigid pi-conjugated moiety and flexible alkyl chains are intrinsically immiscible. Recent studies have shown that such compounds can form a variety of self-organized solid and thermotropic liquid crystalline structures as well as nonassembled liquid forms depending upon the position, number and kinds of attached alkyl chains. Here, we present a brief overview of recent developments of alkylated-pi chemistry, with an emphasis on the relationships between molecular design, self-assembly behavior and applications in optical and optoelectronic devices. We hope this review can serve as a guide and reference for people working in different research areas, including self-assembly and colloid sciences, synthetic and materials chemistry was well as organic electronics.
学科主题	材料科学与物理化学
收录类别	SCI
资助信息	KAKENHI (23685033;25620069;25104011) from MEXT, Japan, Nagase Science and Technology Foundation;the Hundred Talents Program of Chinese Academy of Sciences (Y20245YBR1)
语种	英语
WOS记录号	WOS:000338815200010
公开日期	2014-11-05
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/6618]
专题	兰州化学物理研究所_清洁能源化学与材料实验室
作者单位	1.Natl Inst Mat Sci, Tsukuba, Ibaraki 3050047, Japan 2.Warsaw Univ Technol, Fac Mat Sci & Engn, PL-02507 Warsaw, Poland 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lab Clean Energy Chem & Mat, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Agnieszka Zielinska,Marcin Leonowicz,Li HG,et al. Controlled self-assembly of alkylated-pi compounds for soft materials - Towards optical and optoelectronic applications[J]. Current Opinion in Colloid and Interface Science,2014,19(2):131-139.
APA	Agnieszka Zielinska,Marcin Leonowicz,Li HG,&Takashi Nakanishi.(2014).Controlled self-assembly of alkylated-pi compounds for soft materials - Towards optical and optoelectronic applications.Current Opinion in Colloid and Interface Science,19(2),131-139.
MLA	Agnieszka Zielinska,et al."Controlled self-assembly of alkylated-pi compounds for soft materials - Towards optical and optoelectronic applications".Current Opinion in Colloid and Interface Science 19.2(2014):131-139.