New type of complex alkali and alkaline earth metal borates with isolated (B12O24)(12-) anionic group

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 中国科学院特殊环境功能材料与器件重点试验室

	New type of complex alkali and alkaline earth metal borates with isolated (B12O24)(12-) anionic group
	Wu, Hongping; Yu, Hongwei; Pan, Shilie; Jiao, Anqing; Han, Jian; Wu, Kui; Han, Shujuan; Li, Hongyi
刊名	Dalton Transactions
	2014
卷号	43 期号:12 页码:4886-4891
ISSN号	14779226
通讯作者	Wu, HP
英文摘要	Compounds with isolated anionic groups often exhibit special linear and nonlinear optical properties and possess potential applications such as birefringence, second harmonic generation and stimulated Raman scattering crystals. In this paper, two new alkali and alkaline earth mixed-metal borates, Li3KB4O8 and LiNa2Sr 8B12O24F6Cl, with isolated (B 12O24)^12- anionic groups have been successfully synthesized by spontaneous crystallization. Their structures were determined by single crystal X-ray diffraction and they both crystallize in the same space group, R3. More interestingly, further structure comparison shows that the discovered anhydrous borates with the (B12O24) ^12- groups also crystallize in the same space group R3, which is related with the local symmetry of the (B12O24) ^12- groups. These structural features suggest that the crystal structures of the family of compounds depend more on their anionic groups. In addition, the property characterizations of the two new borates were investigated by TG-DSC, IR and UV-vis-NIR diffuse reflectance.
收录类别	SCI
WOS记录号	WOS:000332390500033
公开日期	2014-11-11
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/3832]
专题	新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室
作者单位	Key Laboratory of Functional Materials and Devices for Special Environments of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, Xinjiang Technical Institute of Physics and Chemistry of CAS, 40-1 South Beijing Road, Urumqi 830011, China
推荐引用方式 GB/T 7714	Wu, Hongping,Yu, Hongwei,Pan, Shilie,et al. New type of complex alkali and alkaline earth metal borates with isolated (B12O24)(12-) anionic group[J]. Dalton Transactions,2014,43(12):4886-4891.
APA	Wu, Hongping.,Yu, Hongwei.,Pan, Shilie.,Jiao, Anqing.,Han, Jian.,...&Li, Hongyi.(2014).New type of complex alkali and alkaline earth metal borates with isolated (B12O24)(12-) anionic group.Dalton Transactions,43(12),4886-4891.
MLA	Wu, Hongping,et al."New type of complex alkali and alkaline earth metal borates with isolated (B12O24)(12-) anionic group".Dalton Transactions 43.12(2014):4886-4891.