Noncentrosymmetric Cubic CsCdBO3 with Bichromophore

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 新疆维吾尔自治区电子信息材料与器件重点实验室

	Noncentrosymmetric Cubic CsCdBO3 with Bichromophore
	Yu, Hongwei; Wu, Hongping; Pan, Shilie; Zhang, Bingbing; Wen, Ming; Yang, Zhihua; Li, Hongyi; Jiang, Xiangzhan
刊名	EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
	2013
卷号	2013 期号:32 页码:5528-5533
关键词	Noncentrosymmetry Borates Nonlinear optics SHG Structure elucidation
ISSN号	1434-1948
中文摘要	The noncentrosymmetric borate CsCdBO3 was synthesized by a solid-state reaction, and its structure was determined by single-crystal X-ray diffraction. The crystal structure is a complicated three-dimensional network composed of CdO6 octahedra, CsO6 octahedra, and BO3 triangles. Interestingly, CsCdBO3 crystallizes in the cubic space group P2(1)3, which is quite rare for borate-containing anisotropic polarized planar BO3 groups. Furthermore, the IR spectrum confirms the presence of BO3 groups. Second harmonic generation (SHG) measurements on powder samples reveal that the SHG response of CsCdBO3 is approximately 0.5x KDP (KH2PO4). Thermal analysis and UV/Vis/NIR diffuse reflectance spectroscopy data, as well as electronic band structure calculations, are also reported.
收录类别	SCI
公开日期	2014-11-11
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/3855]
专题	新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室新疆理化技术研究所_材料物理与化学研究室
作者单位	Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China; Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Yu, Hongwei,Wu, Hongping,Pan, Shilie,et al. Noncentrosymmetric Cubic CsCdBO3 with Bichromophore[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2013,2013(32):5528-5533.
APA	Yu, Hongwei.,Wu, Hongping.,Pan, Shilie.,Zhang, Bingbing.,Wen, Ming.,...&Jiang, Xiangzhan.(2013).Noncentrosymmetric Cubic CsCdBO3 with Bichromophore.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2013(32),5528-5533.
MLA	Yu, Hongwei,et al."Noncentrosymmetric Cubic CsCdBO3 with Bichromophore".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2013.32(2013):5528-5533.