Ruthenium(II) Complex Catalysts Bearing a Pyridyl-Based Benzimidazolyl-Benzotriazolyl Ligand for Transfer Hydrogenation of Ketones

	Ruthenium(II) Complex Catalysts Bearing a Pyridyl-Based Benzimidazolyl-Benzotriazolyl Ligand for Transfer Hydrogenation of Ketones
	Du, Wangming 1; Wu, Ping 1; Wang, Qingfu 1; Yu, Zhengkun 1,2
刊名	organometallics
	2013-05-27
卷号	32 期号:10 页码:3083-3090
通讯作者	余正坤
产权排序	待补充
合作状况	英
英文摘要	air- and moisture-stable ruthenium(h) complexes bearing a unsymmetrical 2-(benzimidazol-2-yl)-6-(benzotriazol-1-yl)pyridine ligand were synthesized and structurally characterized by nmr analysis and xray crystallographic determinations. these complexes have exhibited excellent catalytic activity in the transfer hydrogenation of ketones in refluxing 2-propanol, reaching final tofs up to 176400 h(-1). the corresponding ruh complex was isolated and is proposed as the catalytically active species by controlled experiments. the high catalytic activity of the ru(ii) the complex catalysts is attributed to the hemilabile unsymmetrical coordinating environment around the central metal atom in the complexes and presence of a convertible benzimidazolyl nh functionality in the ligand.
学科主题	物理化学
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, inorganic & nuclear ; chemistry, organic
研究领域[WOS]	chemistry
关键词[WOS]	asymmetric transfer hydrogenation ; pyrazolyl-imidazolyl ligand ; carbonyl-compounds ; efficient catalysts ; iron(ii) complexes ; h-2 hydrogenation ; metal-catalysts ; hydride complex ; spin-crossover ; reduction
收录类别	SCI ; IC ; CCR
资助信息	1，1
原文出处	3090
语种	英语
WOS记录号	WOS:000319650300027
公开日期	2014-09-11
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/119671]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式 GB/T 7714	Du, Wangming,Wu, Ping,Wang, Qingfu,et al. Ruthenium(II) Complex Catalysts Bearing a Pyridyl-Based Benzimidazolyl-Benzotriazolyl Ligand for Transfer Hydrogenation of Ketones[J]. organometallics,2013,32(10):3083-3090.
APA	Du, Wangming,Wu, Ping,Wang, Qingfu,&Yu, Zhengkun.(2013).Ruthenium(II) Complex Catalysts Bearing a Pyridyl-Based Benzimidazolyl-Benzotriazolyl Ligand for Transfer Hydrogenation of Ketones.organometallics,32(10),3083-3090.
MLA	Du, Wangming,et al."Ruthenium(II) Complex Catalysts Bearing a Pyridyl-Based Benzimidazolyl-Benzotriazolyl Ligand for Transfer Hydrogenation of Ketones".organometallics 32.10(2013):3083-3090.