High-Efficiency Photoelectrochemical Properties by a Highly Crystalline CdS-Sensitized ZnO Nanorod Array
Bu, Yuyu1; Chen, Zhuoyuan1; Li, Weibing2; Yu, Jianqiang3
刊名ACS APPLIED MATERIALS & INTERFACES
2013-06-12
卷号5期号:11页码:5097-5104
关键词ZnO nanorod array CdS quantum dot photoelectrochemical performance visible light illumination
ISSN号1944-8244
通讯作者Chen, ZY
中文摘要A ZnO nanorod array with comparatively long nanorods was successfully prepared on a Ti substrate on a T by applying a. hydrothermal method twice. CdS nanoparticles with high crystallinity were deposited onto the surface of ZnO nanorods through a,galvanostatic electrodeposition method. CdS-sensitized ZnO nanorod arrays after being hydrothermally grown twice with the second growth time of 6 h possessed the best photoelectrochemical performance. The photoinduced current densities at a 0 V bias potential are 23.7 and 15.8 mA.cm(-2) under the illumination of simulated sunlight and visible light, respectively. The monochromatic incident photon-to-electron conversion efficiency values at the wavelength of 380-520 nm are in the range of 50-60%, which indicated its high photoelectric conversion efficiency. The contribution from visible light is significantly higher than that from UV light. The prepared photoanodes in the present work exhibit a potential application in photoelectrochemical hydrogen production from water reduction under sunlight.
英文摘要A ZnO nanorod array with comparatively long nanorods was successfully prepared on a Ti substrate on a T by applying a. hydrothermal method twice. CdS nanoparticles with high crystallinity were deposited onto the surface of ZnO nanorods through a,galvanostatic electrodeposition method. CdS-sensitized ZnO nanorod arrays after being hydrothermally grown twice with the second growth time of 6 h possessed the best photoelectrochemical performance. The photoinduced current densities at a 0 V bias potential are 23.7 and 15.8 mA.cm(-2) under the illumination of simulated sunlight and visible light, respectively. The monochromatic incident photon-to-electron conversion efficiency values at the wavelength of 380-520 nm are in the range of 50-60%, which indicated its high photoelectric conversion efficiency. The contribution from visible light is significantly higher than that from UV light. The prepared photoanodes in the present work exhibit a potential application in photoelectrochemical hydrogen production from water reduction under sunlight.
学科主题Science & Technology - Other Topics ; Materials Science
WOS标题词Science & Technology ; Technology
类目[WOS]Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
研究领域[WOS]Science & Technology - Other Topics ; Materials Science
关键词[WOS]TIO2 NANOTUBE ARRAYS ; VISIBLE-LIGHT-DRIVEN ; SOLAR-CELLS ; QUANTUM DOTS ; HYDROGEN GENERATION ; PHOTOCATALYTIC DEGRADATION ; NANOWIRE ARRAYS ; SOLID-SOLUTION ; THIN-FILMS ; WATER
收录类别SCI
原文出处10.1021/am400964c
语种英语
WOS记录号WOS:000320484000082
公开日期2014-07-17
内容类型期刊论文
源URL[http://ir.qdio.ac.cn/handle/337002/16368]  
专题海洋研究所_海洋腐蚀与防护研究发展中心
作者单位1.Chinese Acad Sci, Key Lab Marine Environm Corros & Biofouling, Inst Oceanol, Qingdao 266071, Peoples R China
2.Qingdao Univ Sci & Technol, Sch Environm & Safety Engn, Qingdao 266042, Peoples R China
3.Qingdao Univ, Key Lab New Fiber Mat & Modem Text, Qingdao 266071, Peoples R China
推荐引用方式
GB/T 7714
Bu, Yuyu,Chen, Zhuoyuan,Li, Weibing,et al. High-Efficiency Photoelectrochemical Properties by a Highly Crystalline CdS-Sensitized ZnO Nanorod Array[J]. ACS APPLIED MATERIALS & INTERFACES,2013,5(11):5097-5104.
APA Bu, Yuyu,Chen, Zhuoyuan,Li, Weibing,&Yu, Jianqiang.(2013).High-Efficiency Photoelectrochemical Properties by a Highly Crystalline CdS-Sensitized ZnO Nanorod Array.ACS APPLIED MATERIALS & INTERFACES,5(11),5097-5104.
MLA Bu, Yuyu,et al."High-Efficiency Photoelectrochemical Properties by a Highly Crystalline CdS-Sensitized ZnO Nanorod Array".ACS APPLIED MATERIALS & INTERFACES 5.11(2013):5097-5104.
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