Cu(II)-catalyzed cyclization of alpha-diazo-beta-oxoamides with amines leading to pyrrol-3(2H)-ones

	Cu(II)-catalyzed cyclization of alpha-diazo-beta-oxoamides with amines leading to pyrrol-3(2H)-ones
	Wang ZK ; Bi XH ; Liao PQ ; Liu X ; Dong DW
刊名	chemical communications
	2013
卷号	49 期号:13 页码:1309-1311
关键词	METAL-CATALYZED REACTION SUBSTITUTED PYRROLIN-4-ONES DIAZOAMIDES ENTRY ACIDS DERIVATIVES N-BIS(TRIMETHYLSILYL)METHYL 3-ALKYLIDENEOXINDOLES N-(2-INDOLYL)METHYL CYCLOCONDENSATION
ISSN号	1359-7345
通讯作者	bi xh
中文摘要	a novel cu(ii)-catalyzed cyclization of alpha-diazo-beta-oxoamides with amines has been developed, constituting a straightforward method to construct pyrrol-3(2h)-one rings. the intramolecular hydrogen bonding effect in alpha-diazo-beta-oxoamides plays an essential role in this reaction. a plausible reaction mechanism involving divergent generation and subsequent [2 + 3] cyclization of ketene and alpha-diazoimine intermediates was proposed.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000313663900018
公开日期	2014-04-18
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/50394]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Wang ZK,Bi XH,Liao PQ,et al. Cu(II)-catalyzed cyclization of alpha-diazo-beta-oxoamides with amines leading to pyrrol-3(2H)-ones[J]. chemical communications,2013,49(13):1309-1311.
APA	Wang ZK,Bi XH,Liao PQ,Liu X,&Dong DW.(2013).Cu(II)-catalyzed cyclization of alpha-diazo-beta-oxoamides with amines leading to pyrrol-3(2H)-ones.chemical communications,49(13),1309-1311.
MLA	Wang ZK,et al."Cu(II)-catalyzed cyclization of alpha-diazo-beta-oxoamides with amines leading to pyrrol-3(2H)-ones".chemical communications 49.13(2013):1309-1311.