Employing tripodal carboxylate ligand to construct Co(II) coordination networks modulated by N-donor ligands: syntheses, structures and magnetic properties

	Employing tripodal carboxylate ligand to construct Co(II) coordination networks modulated by N-donor ligands: syntheses, structures and magnetic properties
	Song XZ ; Song SY ; Zhu M ; Hao ZM ; Meng X ; Zhao SN ; Zhang HJ
刊名	dalton transactions
	2013
卷号	42 期号:36 页码:13231-13240
关键词	METAL-ORGANIC FRAMEWORKS HETEROGENEOUS ASYMMETRIC CATALYSIS SPIN-FRUSTRATION LUMINESCENT PROPERTIES BUILDING-BLOCKS SINGLE-CRYSTAL ISOPHTHALIC ACID MN-II POLYMERS COBALT(II)
ISSN号	1477-9226
通讯作者	zhang hj
中文摘要	hydrothermal reaction of a tripodal bridging ligand, 5-(4-carboxyphenoxy)isophthalic acid (h(3)cpia) with cobalt salts modulated by n-donor neutral ligands leads to the formation of six novel coordination networks formulated as {[co-1.5(cpia)(o-bix)](h2o)(1.5)}(n) (1), {[co-2(cpia)(mu-oh)(m-bix)]h2o}(n) (2), {[co-1.5(cpia)(m-bix)]}(n) (3), {[co-1.5(cpia)(p-bix)(0.5)(h2o)]h2o}(n) (4), {[co-2.5(cpia)(hcpia)(4,4'-bpy)(2.5)](h2o)(3)}(n) (5), and {[co-3(cpia)(2)(bpp)(2)]h2o}(n) (6). compound 1 exhibits a two-dimensional, (3,8)-connected layered architecture composed of trinuclear cobalt clusters. compound 2 possesses a three-dimensional dense framework with (3,8)-connected tfz-d topology built from butterfly-shaped tetranuclear co-4(mu(3)-oh)(2)(6+) clusters. similar to compound 1, trinuclear co clusters act as secondary building units to construct the final 2d layered structure modulated by m-bix and bpp ligands in compounds 3 and 6. in compound 4, trinuclear co clusters connected by cpia(3-) anions give rise to two-dimensional layers, which are further pillared by p-bix ligands to the three-dimensional framework. compound 5 features a 2d, (3,4,6)-connected molecular network assembled from alternate binuclear and mononuclear co building blocks. the magnetic investigation indicates that strong antiferromagnetic interactions between cobalt ions are dominant in compounds 2 and 6.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000323274800057
公开日期	2014-04-18
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/50211]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Song XZ,Song SY,Zhu M,et al. Employing tripodal carboxylate ligand to construct Co(II) coordination networks modulated by N-donor ligands: syntheses, structures and magnetic properties[J]. dalton transactions,2013,42(36):13231-13240.
APA	Song XZ.,Song SY.,Zhu M.,Hao ZM.,Meng X.,...&Zhang HJ.(2013).Employing tripodal carboxylate ligand to construct Co(II) coordination networks modulated by N-donor ligands: syntheses, structures and magnetic properties.dalton transactions,42(36),13231-13240.
MLA	Song XZ,et al."Employing tripodal carboxylate ligand to construct Co(II) coordination networks modulated by N-donor ligands: syntheses, structures and magnetic properties".dalton transactions 42.36(2013):13231-13240.