A chemical reaction controlled mechanochemical route to construction of CuO nanoribbons for high performance lithium-ion batteries

	A chemical reaction controlled mechanochemical route to construction of CuO nanoribbons for high performance lithium-ion batteries
	Chen KF ; Xue DF
刊名	physical chemistry chemical physics
	2013
卷号	15 期号:45 页码:19708-19714
关键词	TRANSMISSION ELECTRON-MICROSCOPY ANODE MATERIALS ENERGY-STORAGE CRYSTALLIZATION CU2O NANOPARTICLES OXIDATION NANOSTRUCTURES LITHIATION FRAMEWORKS
ISSN号	1463-9076
通讯作者	xue df
中文摘要	we reported a chemical reaction controlled mechanochemical route to synthesize mass cuo nanosheets by manual grinding in a mortar and pestle, which does not require any solvent, complex apparatus and techniques. the activation of chemical reactions by milling reactants was thus proved, and the energy from mechanical grinding promotes the fast formation of cuo nanoribbons. the resultant materials have preferential nanoscale ribbon-like morphology that can show large capacity and high cycle performance as lithium-ion battery anodes. after 50 cycles, the discharge capacity of cuo nanoribbon electrodes is 614.0 ma h g(-1), with 93% retention of the reversible capacity. the thermodynamic reactions of the cuo battery showed size-dependent characterization. the microstructures of cuo nanosheets and reaction routes can be controlled by the ratio of naoh/cuac2 according to the chemical reactions involved. the intact nanoribbon structure, thin-layer, and hierarchical structures endow present cuo materials with high reversible capacity and excellent cycling performances. the simple, economical, and environmentally friendly mechanochemical route is of great interest in modern synthetic chemistry.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000326470200025
公开日期	2014-04-16
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/50142]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Chen KF,Xue DF. A chemical reaction controlled mechanochemical route to construction of CuO nanoribbons for high performance lithium-ion batteries[J]. physical chemistry chemical physics,2013,15(45):19708-19714.
APA	Chen KF,&Xue DF.(2013).A chemical reaction controlled mechanochemical route to construction of CuO nanoribbons for high performance lithium-ion batteries.physical chemistry chemical physics,15(45),19708-19714.
MLA	Chen KF,et al."A chemical reaction controlled mechanochemical route to construction of CuO nanoribbons for high performance lithium-ion batteries".physical chemistry chemical physics 15.45(2013):19708-19714.