Effects of Poly(Propylene Oxide)-Poly(Ethylene Oxide)-Poly(Propylene Oxide) Triblock Copolymer on the Gelation of Poly(Ethylene Oxide)-Poly(Propylene Oxide)-Poly(Ethylene Oxide) Aqueous Solutions

	Effects of Poly(Propylene Oxide)-Poly(Ethylene Oxide)-Poly(Propylene Oxide) Triblock Copolymer on the Gelation of Poly(Ethylene Oxide)-Poly(Propylene Oxide)-Poly(Ethylene Oxide) Aqueous Solutions
	Xie Y ; Tang JK ; Lu ZY ; Sun ZY ; An LJ
刊名	journal of macromolecular science part b-physics
	2013
卷号	52 期号:9 页码:1183-1197
关键词	PEO BLOCK-COPOLYMER PHASE-BEHAVIOR LIGHT-SCATTERING OXYPROPYLENE OXYETHYLENE) AGGREGATION BEHAVIOR ELECTROMOTIVE-FORCE MICELLE FORMATION MICELLIZATION F127 WATER
ISSN号	0022-2348
通讯作者	sun zy
中文摘要	poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) ((eo)(n)-(po)(m)-(eo)(n)) block copolymers, commercially available as pluronics (basf corp.) and poloxamers (ici corp.), have been widely applied in medicine, biochemistry, and other fields because of their ability to form reversible micelles and physical gels in aqueous solution. generally, for peo-ppo-peo block copolymers with higher ethylene oxide concentration, the micellization and gelation in aqueous solution are easier. however, if we introduce the reverse block copolymer ppo-peo-ppo into peo-ppo-peo aqueous solutions, the micellization and gelation of the system will be more complex. in this work, the reverse block copolymer po14-eo24-po14 (17r4) was added to the pluronics eo20-po70-eo20 (p123), eo100-po65-eo100 (f127), and eo133-po50-eo133 (f108) aqueous solutions with different molar ratios. the rheological properties of different mixtures were measured to study the additive effect on the gelation behavior. the sol-gel transition temperature of the p123, f127, and f108 solutions shifted to a higher temperature when 17r4 was added to the solutions. in addition, the existence of 17r4 greatly affected the stability of gels. these results help to better understand the gelation of pluronic aqueous solutions.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000320981500001
公开日期	2014-04-15
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/49709]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Xie Y,Tang JK,Lu ZY,et al. Effects of Poly(Propylene Oxide)-Poly(Ethylene Oxide)-Poly(Propylene Oxide) Triblock Copolymer on the Gelation of Poly(Ethylene Oxide)-Poly(Propylene Oxide)-Poly(Ethylene Oxide) Aqueous Solutions[J]. journal of macromolecular science part b-physics,2013,52(9):1183-1197.
APA	Xie Y,Tang JK,Lu ZY,Sun ZY,&An LJ.(2013).Effects of Poly(Propylene Oxide)-Poly(Ethylene Oxide)-Poly(Propylene Oxide) Triblock Copolymer on the Gelation of Poly(Ethylene Oxide)-Poly(Propylene Oxide)-Poly(Ethylene Oxide) Aqueous Solutions.journal of macromolecular science part b-physics,52(9),1183-1197.
MLA	Xie Y,et al."Effects of Poly(Propylene Oxide)-Poly(Ethylene Oxide)-Poly(Propylene Oxide) Triblock Copolymer on the Gelation of Poly(Ethylene Oxide)-Poly(Propylene Oxide)-Poly(Ethylene Oxide) Aqueous Solutions".journal of macromolecular science part b-physics 52.9(2013):1183-1197.