Selective hydrogenation of benzonitrile in multiphase reaction systems including compressed carbon dioxide over Ni/Al2O3 catalyst

	Selective hydrogenation of benzonitrile in multiphase reaction systems including compressed carbon dioxide over Ni/Al2O3 catalyst
	Cheng HY ; Meng XC ; Wu CY ; Shan XY ; Yu YC ; Zhao FY
刊名	journal of molecular catalysis a-chemical
	2013
卷号	379 页码:72-79
关键词	PHOSPHINE COMPLEX CATALYSTS ORGANIC-SYNTHESIS WATER NITRILES ACETONITRILE NICKEL PHASE SUPPORTS SOLVENT CO2
ISSN号	1381-1169
通讯作者	zhao fy
中文摘要	selective hydrogenation of benzonitrile was studied with ni/al2o3 in compressed co2, hexane-co2, ethanol-co2 and h2o-co2 systems. the phase behavior and the effect of co2 on the conversion of benzonitrile and the yield of benzylamine were discussed. the reaction rate was retarded in solventless, hexane and ethanol, but accelerated in water in the presence of compressed co2. the decrease in reaction rate was mainly ascribed to the formation of carbamate from benzylamine and the intermediate 1-aminodibenzylamine reacting with co2, and it precipitated out to coat on the surface of catalyst in solventless and hexane, and the dilution effect of compressed co2 in ethanol. but the yield of benzylamine was increased in solventless, hexane and ethanol due to the following nucleophilic addition of benzylamine and benzylimine to n-benzylidenebenzylamine was inhibited. although, the reaction rate increased in water for the enhanced solubility of h-2 and benzonitrile in h2o and decreased mass-transfer resistance in the presence of compressed co2, the yield of benzylamine decreased because of the acidic nature of h2o-co2 favorites the elimination of nh3 and the formation of nh4hco3. accordingly, the possible reaction pathway of benzonitrile hydrogenation was proposed for all the studied systems. (c) 2013 elsevier b.v. all rights reserved.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000326772700011
公开日期	2014-04-15
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/49467]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Cheng HY,Meng XC,Wu CY,et al. Selective hydrogenation of benzonitrile in multiphase reaction systems including compressed carbon dioxide over Ni/Al2O3 catalyst[J]. journal of molecular catalysis a-chemical,2013,379:72-79.
APA	Cheng HY,Meng XC,Wu CY,Shan XY,Yu YC,&Zhao FY.(2013).Selective hydrogenation of benzonitrile in multiphase reaction systems including compressed carbon dioxide over Ni/Al2O3 catalyst.journal of molecular catalysis a-chemical,379,72-79.
MLA	Cheng HY,et al."Selective hydrogenation of benzonitrile in multiphase reaction systems including compressed carbon dioxide over Ni/Al2O3 catalyst".journal of molecular catalysis a-chemical 379(2013):72-79.