Deep-Ultraviolet Nonlinear Optical Materials: Na2Be4B4O11 and LiNa5Be12B12O33

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	Deep-Ultraviolet Nonlinear Optical Materials: Na2Be4B4O11 and LiNa5Be12B12O33
	Huang, HW ; Liu, LJ ; Jin, SF ; Yao, WJ ; Zhang, YH ; Chen, CT
刊名	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
	2013
卷号	135 期号:49 页码:18319
ISSN号	0002-7863
通讯作者	Huang, Hongwei (reprint author), China Univ Geosci, Sch Mat Sci & Technol, Beijing 100083, Peoples R China
中文摘要	Deep-UV coherent light generated by nonlinear optical (NLO) materials possesses highly important applications in photonic technologies. Beryllium borates comprising anionic planar layers have been shown to be the most promising deep UV NLO materials. Here, two novel NLO beryllium borates Na2Be4B4O11 and LiNa5Be12B12O33 have been developed through cationic structural engineering. The most closely arranged [Be2BO5](infinity) planar layers, connected by the flexible [B2O5] groups, have been found in their structures. This structural regulation strategy successfully resulted in the largest second harmonic generation (SHG) effects in the layered beryllium borates, which is similar to 1.3 and 1.4 times that of KDP for Na2Be4B4O11 and LiNa5Be12B12O33, respectively. The deep-UV optical transmittance spectra based on single crystals indicated their short-wavelength cut-offs are down to similar to 170 nm. These results demonstrated that Na2Be4B4O11 and LiNa5Be12B12O33 possess very promising application as deep-UV NLO crystals.
语种	英语
公开日期	2014-01-16
内容类型	期刊论文
源URL	[http://ir.iphy.ac.cn/handle/311004/56866]
专题	物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文
推荐引用方式 GB/T 7714	Huang, HW,Liu, LJ,Jin, SF,et al. Deep-Ultraviolet Nonlinear Optical Materials: Na2Be4B4O11 and LiNa5Be12B12O33[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2013,135(49):18319.
APA	Huang, HW,Liu, LJ,Jin, SF,Yao, WJ,Zhang, YH,&Chen, CT.(2013).Deep-Ultraviolet Nonlinear Optical Materials: Na2Be4B4O11 and LiNa5Be12B12O33.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,135(49),18319.
MLA	Huang, HW,et al."Deep-Ultraviolet Nonlinear Optical Materials: Na2Be4B4O11 and LiNa5Be12B12O33".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 135.49(2013):18319.