Syntheses and characterization of molybdenum/zinc porphyrin dimers bridged by aromatic linkers | |
Song, SN ; Li, DM ; Wu, JF ; Zhuang, CF ; Ding, H ; Song, WB ; Cui, LF ; Cao, GZ ; Liu, GF | |
刊名 | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
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2007 | |
期号 | 13页码:1844 |
ISSN号 | 1434-1948 |
中文摘要 | Two new heterobinuclear porphyrin dimers, namely [{(MoO2)-O-VI}-DBPA-Zn] (1; H(4)DBPA = N,N'-dibenzylidenebis-[4-(10,15,20-triphenyl-21H,23H-porphin-5-yl)phenylamine]) and [((MoO2))-O-VI-PBDA-Zn] (2; H(4)PBDA = N,N'-bis[4-(10,15,20-triphenyl-21H,23H-porphin-5-yl)phenyl]-1,3-benzenedicarboxamide), have been synthesized. These his(porphyrin)s were obtained by treating 5-(p-aminophenyl)-10,15,20-triphenylporphyrinatomolybdenum and -zinc with benzene-1,4-dicarboxaldehyde or benzene-1,3-dicarboxylic acid. They have been characterized by UV/Vis, IR, X-ray photoelectron, luminescence, and H-1 NMR spectroscopy, and their TG-DTA behavior and molar conductances have also been determined. Th cis-dioxomolybdenum(VI) unit in these complexes is contained in one of the porphyrin moieties and zinc(II) ion is tetracoordinated in the other. Their electro-chemical properties have also been investigated in detail. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007). |
收录类别 | SCI |
公开日期 | 2013-09-24 |
内容类型 | 期刊论文 |
源URL | [http://ir.iphy.ac.cn/handle/311004/54273] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Song, SN,Li, DM,Wu, JF,et al. Syntheses and characterization of molybdenum/zinc porphyrin dimers bridged by aromatic linkers[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2007(13):1844. |
APA | Song, SN.,Li, DM.,Wu, JF.,Zhuang, CF.,Ding, H.,...&Liu, GF.(2007).Syntheses and characterization of molybdenum/zinc porphyrin dimers bridged by aromatic linkers.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(13),1844. |
MLA | Song, SN,et al."Syntheses and characterization of molybdenum/zinc porphyrin dimers bridged by aromatic linkers".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .13(2007):1844. |
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