Sr3Sc2Fe2As2O5 as a possible parent compound for FeAs-based superconductors

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	Sr3Sc2Fe2As2O5 as a possible parent compound for FeAs-based superconductors
	Zhu, XY ; Han, F ; Mu, G ; Zeng, B ; Cheng, P ; Shen, B ; Wen, HH
刊名	PHYSICAL REVIEW B
	2009
卷号	79 期号:2
关键词	LIFEAS
ISSN号	1098-0121
通讯作者	Zhu, XY (reprint author), Chinese Acad Sci, Inst Phys, POB 603, Beijing 100190, Peoples R China.
中文摘要	A compound with the FeAs-layers, namely, (Sr3Sc2O5)Fe2As2 (abbreviated as FeAs-32522), was successfully fabricated. It has a layered structure with the space group of I4/mmm, and with the lattice constants a=4.069 A and c=26.876 A. The in-plane Fe ions construct a square lattice which is close to that of other FeAs-based superconductors, such as REFeAsO (RE=rare earth elements) and (Ba,Sr)Fe2As2. However the inter-FeAs-layer spacing in the compound is greatly enlarged. The temperature dependence of resistivity exhibits a weak upturn in the low-temperature region, but a metallic behavior was observed above about 60 K. The magnetic susceptibility shows also a nonmonotonic behavior. Interestingly, the well-known resistivity anomaly which was discovered in all other parent compounds, such as REFeAsO, (Ba,Sr)Fe2As2 and (Sr,Ca,Eu)FeAsF and associated with the spin-density wave/structural transition has not been found in the new system either on the resistivity data or the magnetization data. This could be induced by the large spacing distance between the FeAs-planes, therefore the antiferromagnetic correlation between the moments of Fe ions in neighboring FeAs layers cannot be established. Alternatively it can also be attributed to the self-doping effect between Fe and Sc ions. The Hall coefficient R-H is negative but strongly temperature dependent in wide temperature region, which indicates the dominance of electrical conduction by electronlike charge carriers and probably a multiband effect or a spin related scattering effect. It is found that the magnetoresistance cannot be described by Kohler's rule, which gives further support to above arguments.
收录类别	SCI
资助信息	Natural Science Foundation of China; Ministry of Science and Technology of China [2006CB601000, 2006CB921802]; Chinese Academy of Sciences (ITSNEM)
语种	英语
公开日期	2013-09-24
内容类型	期刊论文
源URL	[http://ir.iphy.ac.cn/handle/311004/52994]
专题	物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文
推荐引用方式 GB/T 7714	Zhu, XY,Han, F,Mu, G,et al. Sr3Sc2Fe2As2O5 as a possible parent compound for FeAs-based superconductors[J]. PHYSICAL REVIEW B,2009,79(2).
APA	Zhu, XY.,Han, F.,Mu, G.,Zeng, B.,Cheng, P.,...&Wen, HH.(2009).Sr3Sc2Fe2As2O5 as a possible parent compound for FeAs-based superconductors.PHYSICAL REVIEW B,79(2).
MLA	Zhu, XY,et al."Sr3Sc2Fe2As2O5 as a possible parent compound for FeAs-based superconductors".PHYSICAL REVIEW B 79.2(2009).