Polypyrrole-iron-oxygen coordination complex as high performance lithium storage material | |
Mao, Y ; Kong, QY ; Guo, BK ; Fang, XP ; Guo, XW ; Shen, L ; Armand, M ; Wang, ZX ; Chen, LQ | |
刊名 | ENERGY & ENVIRONMENTAL SCIENCE |
2011 | |
卷号 | 4期号:9页码:3442 |
关键词 | LI-ION BATTERIES ELECTROCHEMICALLY ACTIVE POLYMERS RECHARGEABLE BATTERIES COMPOSITE CATHODES POLYACETYLENE MORPHOLOGY PARTICLES ELECTRODE EXCHANGE DENSITY |
ISSN号 | 1754-5692 |
通讯作者 | Mao, Y (reprint author), Chinese Acad Sci, Inst Phys, Lab Solid State Ion, POB 603, Beijing 100190, Peoples R China. |
中文摘要 | Current lithium ion battery (LIB) technologies are all based on inorganic electrodes though organic materials have been hyped as electrodes for years. Disadvantages such as low specific capacity and poor rate performance hinder their applications. Here we report a novel high-performance organometallic lithium-storage material, a polypyrrole-iron-oxygen (PPy-Fe-O) coordination complex. Extended X-ray absorption fine structure (EXAFS) spectroscopy and density functional theory (DFT) calculations indicate that this complex has a multilayer structure. The strong and stable intralayer Fe-N coordination permits the material to possess high specific capacity, the high reversibility of its interlayer Fe-O-Fe interaction during cycling ensures its high cycling stability and the conducting PPy matrix endows it with outstanding rate performance. These findings pave the way to constructing a new type of high-performance organic anode materials for LIBs. |
收录类别 | SCI |
资助信息 | National 973 Program of China [2009CB220100]; National 863 Program of China [2009AA033101]; National Natural Science Foundation of China (NSFC) [20974120] |
语种 | 英语 |
公开日期 | 2013-09-24 |
内容类型 | 期刊论文 |
源URL | [http://ir.iphy.ac.cn/handle/311004/51148] |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Mao, Y,Kong, QY,Guo, BK,et al. Polypyrrole-iron-oxygen coordination complex as high performance lithium storage material[J]. ENERGY & ENVIRONMENTAL SCIENCE,2011,4(9):3442. |
APA | Mao, Y.,Kong, QY.,Guo, BK.,Fang, XP.,Guo, XW.,...&Chen, LQ.(2011).Polypyrrole-iron-oxygen coordination complex as high performance lithium storage material.ENERGY & ENVIRONMENTAL SCIENCE,4(9),3442. |
MLA | Mao, Y,et al."Polypyrrole-iron-oxygen coordination complex as high performance lithium storage material".ENERGY & ENVIRONMENTAL SCIENCE 4.9(2011):3442. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论