Eu doping effects on structural and magnetic properties of (Sr2-xEux)FeMoO6 compounds | |
Zhang, Q ; Xiao, YG ; Xu, ZF ; Liu, GY ; Li, JB ; Rao, GH | |
刊名 | JOURNAL OF SOLID STATE CHEMISTRY |
2010 | |
卷号 | 183期号:10页码:2432 |
关键词 | NEUTRON POWDER DIFFRACTION DOUBLE-PEROVSKITE TRANSPORT-PROPERTIES PHASE-TRANSITIONS SR2FEMOO6 MAGNETORESISTANCE OXIDE |
ISSN号 | 0022-4596 |
通讯作者 | Rao, GH: Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China. |
中文摘要 | Double perovskite compounds (Sr2-xEux)FeMoO6 (0 <= x <= 0.3) were prepared by solid-state reaction at high temperature. Crystal structure, magnetic and transport properties of the compounds were investigated. The crystal structure of the compounds changes from an 14/m lattice to an Fm (3) over barm lattice around x=0.1. The unit-cell volume decreases with the doping level in both the 14/m lattice and the Fm (3) over barm lattice. The resistivity of the compounds shows a metal semiconductor transition, and the transition temperature TM-S increases with the doping level. However, Curie temperature (T-C) of the compounds exhibits a weak dependence on the doping level. The saturation magnetization (M-5) at 100 K varies almost linearly with the anti-site defect concentration and agrees well with the simple FIM model. In contrast to the Ce-, Pr-, Nd- and Sm-doped Sr2FeMoO6, the difference of M-S of (Sr2-xEu)FeMoO6 between 5 and 100 K indicates that the moment of Eu3+ is antiparellel to that of Fe3+ at low temperature. (C) 2010 Elsevier Inc. All rights reserved. |
收录类别 | SCI |
资助信息 | MOST [2007CB925003]; National Natural Science Foundation of China [50872148] |
语种 | 英语 |
公开日期 | 2013-09-17 |
内容类型 | 期刊论文 |
源URL | [http://ir.iphy.ac.cn/handle/311004/37588] |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Zhang, Q,Xiao, YG,Xu, ZF,et al. Eu doping effects on structural and magnetic properties of (Sr2-xEux)FeMoO6 compounds[J]. JOURNAL OF SOLID STATE CHEMISTRY,2010,183(10):2432. |
APA | Zhang, Q,Xiao, YG,Xu, ZF,Liu, GY,Li, JB,&Rao, GH.(2010).Eu doping effects on structural and magnetic properties of (Sr2-xEux)FeMoO6 compounds.JOURNAL OF SOLID STATE CHEMISTRY,183(10),2432. |
MLA | Zhang, Q,et al."Eu doping effects on structural and magnetic properties of (Sr2-xEux)FeMoO6 compounds".JOURNAL OF SOLID STATE CHEMISTRY 183.10(2010):2432. |
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