Hydrothermal syntheses and structures of first examples of lanthanide 7,8,4 '-tricarboxymethoxyisoflavone coordination polymers

CORC > 过程工程研究所 > 中国科学院过程工程研究所 > 湿法冶金清洁生产技术国家工程实验室

	Hydrothermal syntheses and structures of first examples of lanthanide 7,8,4 '-tricarboxymethoxyisoflavone coordination polymers
	Wang, Yibo 1,2; Gao, Lihua 2; Han, Lijun 1; Zhang, Suojiang 1; Feng, Lujia 2
刊名	JOURNAL OF MOLECULAR STRUCTURE
	2009-12-16
卷号	938 期号:1-3 页码:214-220
关键词	Hydrothermal synthesis Coordination polymers Lanthanides Carboxylate ligands X-ray diffraction
ISSN号	0022-2860
通讯作者	Zhang, SJ
英文摘要	Two novel isostructure open frameworks of Ln(III), [Ln(L)(H(2)O) 1 5H(2)O](n), [Ln = Pr(1), Eu(2)], have been successfully synthesized using multi functional organic compound 7,8,4'-tricarboxymethoxyisoflavone (L) as a linker through hydrothermal technique. Compounds 1 and 2 consist of 2D networks, which are further assembled into 3D architecture with 1D channels constructed by coordination bonds and the lattice water molecules array in lines occupying these voids via hydrogen bonds. in these compounds, L only exhibit one coordination mode coordinating to Ln(III). and four oxygen atoms from two carboxylate groups and two carboxymethoxy groups of one L coordinate to one Ln(III), simultaneously. The thermogravimetric analyses of these compounds show that the coordinated water and lattice water are lost in two steps, and the final residues are lanthanide oxides (C) 2009 Elsevier B.V. All rights reserved.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Physical
研究领域[WOS]	Chemistry
关键词[WOS]	METAL-ORGANIC FRAMEWORK ; CRYSTAL-STRUCTURE ; BUILDING UNITS ; DESIGN ; CHEMISTRY ; ACID ; ISOFLAVONES ; COMPLEXES ; MOLECULES ; CHANNELS
收录类别	SCI
语种	英语
WOS记录号	WOS:000272896300032
公开日期	2013-11-28
内容类型	期刊论文
版本	出版稿
源URL	[http://ir.ipe.ac.cn/handle/122111/6529]
专题	过程工程研究所_湿法冶金清洁生产技术国家工程实验室
作者单位	1.Chinese Acad Sci, Inst Proc Engn, Res Lab Green Chem & Technol, Beijing 100080, Peoples R China 2.Beijing Technol & Business Univ, Sch Chem & Environm Engn, Beijing 100037, Peoples R China
推荐引用方式 GB/T 7714	Wang, Yibo,Gao, Lihua,Han, Lijun,et al. Hydrothermal syntheses and structures of first examples of lanthanide 7,8,4 '-tricarboxymethoxyisoflavone coordination polymers[J]. JOURNAL OF MOLECULAR STRUCTURE,2009,938(1-3):214-220.
APA	Wang, Yibo,Gao, Lihua,Han, Lijun,Zhang, Suojiang,&Feng, Lujia.(2009).Hydrothermal syntheses and structures of first examples of lanthanide 7,8,4 '-tricarboxymethoxyisoflavone coordination polymers.JOURNAL OF MOLECULAR STRUCTURE,938(1-3),214-220.
MLA	Wang, Yibo,et al."Hydrothermal syntheses and structures of first examples of lanthanide 7,8,4 '-tricarboxymethoxyisoflavone coordination polymers".JOURNAL OF MOLECULAR STRUCTURE 938.1-3(2009):214-220.