AU Nanoparticles Immobilized on Black Phosphorus Intercalated Spherical Covalent Organic Frameworks as Highly Active Catalysts for Flow-Through Reduction of 4-Nitrophenol
Xiao, Fengyan3; Pan, Dawei1,2,4; Wang, Ning2,4
刊名SSRN
2023
关键词Catalyst activity Microspheres Nanosheets Organic pollutants Phosphorus Synthesis (chemical)
ISSN号15565068
DOI10.2139/ssrn.4525234
英文摘要The unique structure and morphology of covalent organic frameworks (COFs) show great potential as active substrates to support noble metals for catalytic application. However, the applications are restricted by their catalytic activity due to the weak conductivity of COFs. Here, conductive black phosphorus was intercalated inside the spherical COFs (SCOFs) during their synthesis process, followed by the immobilization of Au nanoparticles (Au NPs) to construct Au NPs/BP/SCOFs microspheres. A fast and stable flow-through catalysis towards 4-nitrophenol was obtained due to the design of conductive BP nanosheets intercalated SCOFs microspheres with enhanced electron transfer and stable structure. Our strategy to design the conductive BP nanosheets intercalated SCOFs microspheres would develop a new route to improve the catalytic activity for highly efficient conversion nitro-aromatic organic pollutants. © 2023, The Authors. All rights reserved.
语种英语
内容类型期刊论文
源URL[http://ir.yic.ac.cn/handle/133337/34308]  
专题烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室
作者单位1.University of Chinese Academy of Sciences, Beijing; 100049, China
2.CAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Shandong, Yantai; 264003, China;
3.Yantai Institute of Coastal Zone Research, China;
4.Shandong Key Laboratory of Coastal Environmental Processes, Shandong, Yantai; 264003, China;
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Xiao, Fengyan,Pan, Dawei,Wang, Ning. AU Nanoparticles Immobilized on Black Phosphorus Intercalated Spherical Covalent Organic Frameworks as Highly Active Catalysts for Flow-Through Reduction of 4-Nitrophenol[J]. SSRN,2023.
APA Xiao, Fengyan,Pan, Dawei,&Wang, Ning.(2023).AU Nanoparticles Immobilized on Black Phosphorus Intercalated Spherical Covalent Organic Frameworks as Highly Active Catalysts for Flow-Through Reduction of 4-Nitrophenol.SSRN.
MLA Xiao, Fengyan,et al."AU Nanoparticles Immobilized on Black Phosphorus Intercalated Spherical Covalent Organic Frameworks as Highly Active Catalysts for Flow-Through Reduction of 4-Nitrophenol".SSRN (2023).
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