ZnCl2 induced hierarchical porous carbon for zinc-ion hybrid supercapacitors
Yang, Shuhua4; Cui, Yanwei4; Yang, Guangxu4; Zhao, Songfang4; Wang, Jieqiang4; Zhao, Degang4; Yang, Chao3; Wang, Xiutong1,2; Cao, Bingqiang4
刊名JOURNAL OF POWER SOURCES
2023-01-15
卷号554页码:6
关键词Zinc-ion hybrid supercapacitors ZnCl2 Corncob cellulose Quasi-solid-state flexible hybrid supercapacitor
ISSN号0378-7753
DOI10.1016/j.jpowsour.2022.232347
通讯作者Yang, Shuhua(yangshuhua78@163.com)
英文摘要Carbon-based cathode materials are highly desired for zinc-ion hybrid supercapacitors (ZHSs) due to their rich sources and low production cost. Here, a ZnCl2 induced hierarchical porous carbon is developed from corncob cellulose by a single-step activation process. The suitable micropores are conducive to the adsorption/desorption of zinc ions for the high energy storage, whereas the sufficient mesopores are in favor of the rapid migration of electrolyte ions for the high-rate performance, both which can effectively improve the performance of ZHSs. The ZHS fabricated with the optimized hierarchical porous carbon (ZnHPC-0.5) exhibits a high specific capacity of 120.3 mAh g(-1) and a high energy density of 103.2 Wh kg(-1). After 10000 cycles at a high current density of 5 A g(-1), the capacity retention is 99.2%. In addition, the assembled quasi-solid-state flexible hybrid supercapacitor (QSSF-ZHS) also shows high specific capacities, satisfactory mechanical properties, and good application prospects.
资助项目Shandong Provincial Natural Science Foundation[ZR2022ME181] ; NSFC[51702123] ; Shandong Province Higher Educational Youths Innovation Science and Technology Program[2019KJA018] ; University of Jinan Science and Technology Planning Project[XKY2034] ; University of Jinan
WOS研究方向Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science
语种英语
出版者ELSEVIER
WOS记录号WOS:000891788300004
内容类型期刊论文
源URL[http://ir.qdio.ac.cn/handle/337002/181006]  
专题海洋研究所_海洋腐蚀与防护研究发展中心
通讯作者Yang, Shuhua
作者单位1.Chinese Acad Sci, Ctr Ocean Mega Sci, Qingdao 266071, Peoples R China
2.Chinese Acad Sci, Key Lab Marine Environm Corros & Biofouling, Inst Oceanol, Qingdao 266071, Peoples R China
3.Qufu Normal Univ, Sch Phys & Phys Engn, Qufu 273165, Shandong, Peoples R China
4.Univ Jinan, Mat Ctr Energy & Photoelectrochem Convers, Sch Mat Sci & Engn, Jinan 250022, Peoples R China
推荐引用方式
GB/T 7714
Yang, Shuhua,Cui, Yanwei,Yang, Guangxu,et al. ZnCl2 induced hierarchical porous carbon for zinc-ion hybrid supercapacitors[J]. JOURNAL OF POWER SOURCES,2023,554:6.
APA Yang, Shuhua.,Cui, Yanwei.,Yang, Guangxu.,Zhao, Songfang.,Wang, Jieqiang.,...&Cao, Bingqiang.(2023).ZnCl2 induced hierarchical porous carbon for zinc-ion hybrid supercapacitors.JOURNAL OF POWER SOURCES,554,6.
MLA Yang, Shuhua,et al."ZnCl2 induced hierarchical porous carbon for zinc-ion hybrid supercapacitors".JOURNAL OF POWER SOURCES 554(2023):6.
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