A rare potassium-rich zirconium fluorophosphonate with high Eu3+ adsorption capacities from acidic solutions

doi:10.1039/d2dt01291j

	A rare potassium-rich zirconium fluorophosphonate with high Eu3+ adsorption capacities from acidic solutions
	Zhang, Jiarong 1,2,3,4; Chen, Long 1,2; Chen, Lanhua 1,2; Chen, Lei 1,2; Zhang, Yugang 1,2; Chen, Changlun 3,4; Chai, Zhifang 1,2; Wang, Shuao 1,2
刊名	DALTON TRANSACTIONS
	2022-08-24
ISSN号	1477-9226
DOI	10.1039/d2dt01291j
通讯作者	Chen, Changlun(clchen@ipp.ac.cn) ; Wang, Shuao(shuaowang@suda.edu.cn)
英文摘要	A novel 3D potassium-containing zirconium fluorophosphonate K2Zr[CH2(PO3)(2)]F-2 (SZ-8) was successfully synthesized as single crystals via a solvothermal method using a mixture of nitric acid and potassium nitrate as mineralizers. SZ-8 can adsorb 110.6 and 57 mg g(-1) of Eu3+ in pH 2 and pH 1 solutions respectively, highlighting its potential remediation for radionuclides with high charges. SZ-8 not only possesses superior Eu3+ removal capacity under strongly acidic conditions, but also provides a universal synthesis strategy for crystalline zirconium phosphonates with inorganic counterions.
资助项目	National Natural Science Foundation of China[21825601] ; National Natural Science Foundation of China[21790374] ; National Natural Science Foundation of China[21906113] ; National Natural Science Foundation of China[22176139] ; National Natural Science Foundation of China[U1967217] ; National Key R&D Program of China[2018YFB1900203]
WOS关键词	ION-EXCHANGE ; EFFICIENT REMOVAL ; PROTON CONDUCTIVITY ; CRYSTAL-STRUCTURE ; METAL PHOSPHATES ; POWDER DATA ; PHOSPHONATE ; FRAMEWORK ; EUROPIUM ; SORPTION
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000850819100001
资助机构	National Natural Science Foundation of China ; National Key R&D Program of China
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/131912]
专题	中国科学院合肥物质科学研究院
通讯作者	Chen, Changlun; Wang, Shuao
作者单位	1.Soochow Univ, Collaborat Innovat Ctr Radiat Med, Jiangsu Higher Educ Inst, Suzhou 215123, Peoples R China 2.Soochow Univ, Sch Radiol & Interdisciplinary Sci RAD X, State Key Lab Radiat Med & Protect, Suzhou 215123, Peoples R China 3.Univ Sci & Technol China, Hefei 230026, Peoples R China 4.Chinese Acad Sci, Inst Plasma Phys, HFIPS, POB 1126, Hefei 230031, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Jiarong,Chen, Long,Chen, Lanhua,et al. A rare potassium-rich zirconium fluorophosphonate with high Eu3+ adsorption capacities from acidic solutions[J]. DALTON TRANSACTIONS,2022.
APA	Zhang, Jiarong.,Chen, Long.,Chen, Lanhua.,Chen, Lei.,Zhang, Yugang.,...&Wang, Shuao.(2022).A rare potassium-rich zirconium fluorophosphonate with high Eu3+ adsorption capacities from acidic solutions.DALTON TRANSACTIONS.
MLA	Zhang, Jiarong,et al."A rare potassium-rich zirconium fluorophosphonate with high Eu3+ adsorption capacities from acidic solutions".DALTON TRANSACTIONS (2022).